Microbial Synthesis of <i>Neo-Allo</i>-Ocimene by Celery-Derived <i>Neo-Allo</i>-Ocimene Synthase

<i>Neo-allo</i>-ocimene is a monoterpene which could be applied in pesticides, fragrances, and sustainable polymers. In this study, we mined a terpene synthase, AgTPS40, from the transcriptome of celery leaf tissues. Through sequence and phylogenetic analysis, AgTPS40 was characterized a...

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Main Authors: Zheng Liu, Ting Gao, Shaoheng Bao, Penggang Han, Ge Yao, Tianyu Song, Longbao Zhu, Chang Chen, Hui Jiang
Format: Article
Language:English
Published: MDPI AG 2025-03-01
Series:Fermentation
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Online Access:https://www.mdpi.com/2311-5637/11/3/153
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author Zheng Liu
Ting Gao
Shaoheng Bao
Penggang Han
Ge Yao
Tianyu Song
Longbao Zhu
Chang Chen
Hui Jiang
author_facet Zheng Liu
Ting Gao
Shaoheng Bao
Penggang Han
Ge Yao
Tianyu Song
Longbao Zhu
Chang Chen
Hui Jiang
author_sort Zheng Liu
collection DOAJ
description <i>Neo-allo</i>-ocimene is a monoterpene which could be applied in pesticides, fragrances, and sustainable polymers. In this study, we mined a terpene synthase, AgTPS40, from the transcriptome of celery leaf tissues. Through sequence and phylogenetic analysis, AgTPS40 was characterized as a monoterpene synthase. The <i>AgTPS40</i> gene was introduced into a heterologous mevalonate pathway hosted in <i>Escherichia coli</i> to enable terpene production. Gas chromatography–mass spectrometry analysis confirmed that AgTPS40 catalyzes the formation of <i>neo-allo</i>-ocimene, marking the first reported identification of a <i>neo-allo</i>-ocimene synthase. Subsequently, we optimized the fermentation conditions and achieved a yield of 933.35 mg/L in a 1 L shake flask, which represents the highest reported titer of <i>neo-allo</i>-ocimene to date. These results reveal the molecular basis of <i>neo-allo</i>-ocimene synthesis in celery and provide a sustainable way to obtain this compound.
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issn 2311-5637
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publishDate 2025-03-01
publisher MDPI AG
record_format Article
series Fermentation
spelling doaj-art-06e70df8ce984ff99bcabe6ee29c26132025-08-20T02:42:29ZengMDPI AGFermentation2311-56372025-03-0111315310.3390/fermentation11030153Microbial Synthesis of <i>Neo-Allo</i>-Ocimene by Celery-Derived <i>Neo-Allo</i>-Ocimene SynthaseZheng Liu0Ting Gao1Shaoheng Bao2Penggang Han3Ge Yao4Tianyu Song5Longbao Zhu6Chang Chen7Hui Jiang8School of Biological and Food Engineering, Anhui Polytechnic University, Wuhu 241000, ChinaState Key Laboratory of NBC Protection for Civilian, Beijing 102205, ChinaState Key Laboratory of NBC Protection for Civilian, Beijing 102205, ChinaState Key Laboratory of NBC Protection for Civilian, Beijing 102205, ChinaState Key Laboratory of NBC Protection for Civilian, Beijing 102205, ChinaState Key Laboratory of NBC Protection for Civilian, Beijing 102205, ChinaSchool of Biological and Food Engineering, Anhui Polytechnic University, Wuhu 241000, ChinaState Key Laboratory of NBC Protection for Civilian, Beijing 102205, ChinaState Key Laboratory of NBC Protection for Civilian, Beijing 102205, China<i>Neo-allo</i>-ocimene is a monoterpene which could be applied in pesticides, fragrances, and sustainable polymers. In this study, we mined a terpene synthase, AgTPS40, from the transcriptome of celery leaf tissues. Through sequence and phylogenetic analysis, AgTPS40 was characterized as a monoterpene synthase. The <i>AgTPS40</i> gene was introduced into a heterologous mevalonate pathway hosted in <i>Escherichia coli</i> to enable terpene production. Gas chromatography–mass spectrometry analysis confirmed that AgTPS40 catalyzes the formation of <i>neo-allo</i>-ocimene, marking the first reported identification of a <i>neo-allo</i>-ocimene synthase. Subsequently, we optimized the fermentation conditions and achieved a yield of 933.35 mg/L in a 1 L shake flask, which represents the highest reported titer of <i>neo-allo</i>-ocimene to date. These results reveal the molecular basis of <i>neo-allo</i>-ocimene synthesis in celery and provide a sustainable way to obtain this compound.https://www.mdpi.com/2311-5637/11/3/153celery<i>neo-allo</i>-ocimenemonoterpene synthasebiosynthesis
spellingShingle Zheng Liu
Ting Gao
Shaoheng Bao
Penggang Han
Ge Yao
Tianyu Song
Longbao Zhu
Chang Chen
Hui Jiang
Microbial Synthesis of <i>Neo-Allo</i>-Ocimene by Celery-Derived <i>Neo-Allo</i>-Ocimene Synthase
Fermentation
celery
<i>neo-allo</i>-ocimene
monoterpene synthase
biosynthesis
title Microbial Synthesis of <i>Neo-Allo</i>-Ocimene by Celery-Derived <i>Neo-Allo</i>-Ocimene Synthase
title_full Microbial Synthesis of <i>Neo-Allo</i>-Ocimene by Celery-Derived <i>Neo-Allo</i>-Ocimene Synthase
title_fullStr Microbial Synthesis of <i>Neo-Allo</i>-Ocimene by Celery-Derived <i>Neo-Allo</i>-Ocimene Synthase
title_full_unstemmed Microbial Synthesis of <i>Neo-Allo</i>-Ocimene by Celery-Derived <i>Neo-Allo</i>-Ocimene Synthase
title_short Microbial Synthesis of <i>Neo-Allo</i>-Ocimene by Celery-Derived <i>Neo-Allo</i>-Ocimene Synthase
title_sort microbial synthesis of i neo allo i ocimene by celery derived i neo allo i ocimene synthase
topic celery
<i>neo-allo</i>-ocimene
monoterpene synthase
biosynthesis
url https://www.mdpi.com/2311-5637/11/3/153
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