Heteroatom doping in 2D MXenes for energy storage/conversion applications

MXenes (inorganic metal carbides, nitrides, and carbonitrides) are currently the rising star of two-dimensional (2D) family. After its discovery in 2011, initial research was concentrated on pristine MXenes only. However, in the last few years, the MXene family has been expanded with the exploration...

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Main Authors: Sumanta Sahoo, Rajesh Kumar, Iftikhar Hussain, Kaili Zhang
Format: Article
Language:English
Published: KeAi Communications Co. Ltd. 2024-12-01
Series:Advanced Powder Materials
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Online Access:http://www.sciencedirect.com/science/article/pii/S2772834X24000770
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author Sumanta Sahoo
Rajesh Kumar
Iftikhar Hussain
Kaili Zhang
author_facet Sumanta Sahoo
Rajesh Kumar
Iftikhar Hussain
Kaili Zhang
author_sort Sumanta Sahoo
collection DOAJ
description MXenes (inorganic metal carbides, nitrides, and carbonitrides) are currently the rising star of two-dimensional (2D) family. After its discovery in 2011, initial research was concentrated on pristine MXenes only. However, in the last few years, the MXene family has been expanded with the exploration of novel double MXenes, synthesis of non-Ti MXenes, and heteroatom doping of MXenes. The current review article delivers an exclusive overview of the current research trends on the heteroatom doping of MXenes. The recent advances in heteroatom doping of MXenes (majorly Ti-MXenes) for energy storage/conversion applications including secondary batteries (Li-ion, Li–S, Na–S, Na-ion, K-ion, Zn-ion batteries), supercapacitors, electrocatalysis, etc. are summarized. A brief overview of the defects as well as doping in various 2D materials is included in the manuscript. Various doping strategies of MXenes are outlined. Moreover, the impact of artificial intelligence/machine learning on MXene research is also concisely discussed. Additionally, the advantages of doping on MXenes are discussed in detail. Lastly, the existing challenges and future prospects of doped MXenes are addressed. It is expected that the current review will open new prospects for the fabrication of advanced energy devices through heteroatom doping of MXenes.
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spelling doaj-art-06d2f42d44514da6be9c76fe7eb13c552025-08-20T02:51:19ZengKeAi Communications Co. Ltd.Advanced Powder Materials2772-834X2024-12-013610024610.1016/j.apmate.2024.100246Heteroatom doping in 2D MXenes for energy storage/conversion applicationsSumanta Sahoo0Rajesh Kumar1Iftikhar Hussain2Kaili Zhang3School of Chemical Engineering, Yeungnam University, 280 Daehak-ro, Gyeongsan, Gyeongbuk, 38541, Republic of Korea; Corresponding author.Department of Mechanical Engineering, Indian Institute of Technology, Kanpur, 208016, Uttar Pradesh, India; Corresponding author.Department of Mechanical Engineering, City University of Hong Kong, 83 Tat Chee Avenue, Kowloon, Hong Kong; Corresponding author.Department of Mechanical Engineering, City University of Hong Kong, 83 Tat Chee Avenue, Kowloon, Hong Kong; Corresponding author.MXenes (inorganic metal carbides, nitrides, and carbonitrides) are currently the rising star of two-dimensional (2D) family. After its discovery in 2011, initial research was concentrated on pristine MXenes only. However, in the last few years, the MXene family has been expanded with the exploration of novel double MXenes, synthesis of non-Ti MXenes, and heteroatom doping of MXenes. The current review article delivers an exclusive overview of the current research trends on the heteroatom doping of MXenes. The recent advances in heteroatom doping of MXenes (majorly Ti-MXenes) for energy storage/conversion applications including secondary batteries (Li-ion, Li–S, Na–S, Na-ion, K-ion, Zn-ion batteries), supercapacitors, electrocatalysis, etc. are summarized. A brief overview of the defects as well as doping in various 2D materials is included in the manuscript. Various doping strategies of MXenes are outlined. Moreover, the impact of artificial intelligence/machine learning on MXene research is also concisely discussed. Additionally, the advantages of doping on MXenes are discussed in detail. Lastly, the existing challenges and future prospects of doped MXenes are addressed. It is expected that the current review will open new prospects for the fabrication of advanced energy devices through heteroatom doping of MXenes.http://www.sciencedirect.com/science/article/pii/S2772834X24000770MXeneDopingSupercapacitorSecondary batteryElectrocatalysis
spellingShingle Sumanta Sahoo
Rajesh Kumar
Iftikhar Hussain
Kaili Zhang
Heteroatom doping in 2D MXenes for energy storage/conversion applications
Advanced Powder Materials
MXene
Doping
Supercapacitor
Secondary battery
Electrocatalysis
title Heteroatom doping in 2D MXenes for energy storage/conversion applications
title_full Heteroatom doping in 2D MXenes for energy storage/conversion applications
title_fullStr Heteroatom doping in 2D MXenes for energy storage/conversion applications
title_full_unstemmed Heteroatom doping in 2D MXenes for energy storage/conversion applications
title_short Heteroatom doping in 2D MXenes for energy storage/conversion applications
title_sort heteroatom doping in 2d mxenes for energy storage conversion applications
topic MXene
Doping
Supercapacitor
Secondary battery
Electrocatalysis
url http://www.sciencedirect.com/science/article/pii/S2772834X24000770
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AT rajeshkumar heteroatomdopingin2dmxenesforenergystorageconversionapplications
AT iftikharhussain heteroatomdopingin2dmxenesforenergystorageconversionapplications
AT kailizhang heteroatomdopingin2dmxenesforenergystorageconversionapplications