The effect of antimony presence in anodic copper on kinetics and mechanism of anodic dissolution and cathodic deposition of copper

The influence of the presence of Sb atoms, as foreign metal atoms in anode copper, on kinetics, and, on the mechanism of anodic dissolution and cathodic deposition of copper in acidic sulfate solution has been investigated. The galvanostatic single-pulse method has been used. Results indicate that p...

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Main Authors: Stanković Z.D., Cvetkovski V., Vuković M.
Format: Article
Language:English
Published: University of Belgrade, Technical Faculty, Bor 2008-01-01
Series:Journal of Mining and Metallurgy. Section B: Metallurgy
Subjects:
Online Access:http://www.doiserbia.nb.rs/img/doi/1450-5339/2008/1450-53390801107S.pdf
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author Stanković Z.D.
Cvetkovski V.
Vuković M.
author_facet Stanković Z.D.
Cvetkovski V.
Vuković M.
author_sort Stanković Z.D.
collection DOAJ
description The influence of the presence of Sb atoms, as foreign metal atoms in anode copper, on kinetics, and, on the mechanism of anodic dissolution and cathodic deposition of copper in acidic sulfate solution has been investigated. The galvanostatic single-pulse method has been used. Results indicate that presence of Sb atoms in anode copper increase the exchange current density as determined from the Tafel analysis of the electrode reaction. It is attributed to the increase of the crystal lattice parameter determined from XRD analysis of the electrode material.
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publisher University of Belgrade, Technical Faculty, Bor
record_format Article
series Journal of Mining and Metallurgy. Section B: Metallurgy
spelling doaj-art-06894b2381f248188227cdf59e7977f22025-02-02T09:14:11ZengUniversity of Belgrade, Technical Faculty, BorJournal of Mining and Metallurgy. Section B: Metallurgy1450-53392008-01-0144110711410.2298/JMMB0801107SThe effect of antimony presence in anodic copper on kinetics and mechanism of anodic dissolution and cathodic deposition of copperStanković Z.D.Cvetkovski V.Vuković M.The influence of the presence of Sb atoms, as foreign metal atoms in anode copper, on kinetics, and, on the mechanism of anodic dissolution and cathodic deposition of copper in acidic sulfate solution has been investigated. The galvanostatic single-pulse method has been used. Results indicate that presence of Sb atoms in anode copper increase the exchange current density as determined from the Tafel analysis of the electrode reaction. It is attributed to the increase of the crystal lattice parameter determined from XRD analysis of the electrode material.http://www.doiserbia.nb.rs/img/doi/1450-5339/2008/1450-53390801107S.pdfcopperanodic dissolitioncahodic depositionantimonylattice parameter
spellingShingle Stanković Z.D.
Cvetkovski V.
Vuković M.
The effect of antimony presence in anodic copper on kinetics and mechanism of anodic dissolution and cathodic deposition of copper
Journal of Mining and Metallurgy. Section B: Metallurgy
copper
anodic dissolition
cahodic deposition
antimony
lattice parameter
title The effect of antimony presence in anodic copper on kinetics and mechanism of anodic dissolution and cathodic deposition of copper
title_full The effect of antimony presence in anodic copper on kinetics and mechanism of anodic dissolution and cathodic deposition of copper
title_fullStr The effect of antimony presence in anodic copper on kinetics and mechanism of anodic dissolution and cathodic deposition of copper
title_full_unstemmed The effect of antimony presence in anodic copper on kinetics and mechanism of anodic dissolution and cathodic deposition of copper
title_short The effect of antimony presence in anodic copper on kinetics and mechanism of anodic dissolution and cathodic deposition of copper
title_sort effect of antimony presence in anodic copper on kinetics and mechanism of anodic dissolution and cathodic deposition of copper
topic copper
anodic dissolition
cahodic deposition
antimony
lattice parameter
url http://www.doiserbia.nb.rs/img/doi/1450-5339/2008/1450-53390801107S.pdf
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