Synthesis and biological evaluation for some metal complexes with a new ligand (E)-3-(((2-amino-4-methylphenyl)imino)methyl)-4H-chromen-4-one
Complexes of Co(II), Ni(II), Cu(II) Zn(II), and Cd (II) with the ligand 3-(((2-amino-4-methylphenyl)imino)methyl)-4H-chromen-4-one derived 3-formyl chromone with 4-methyl-O-phenylenediamine were synthesized and characterized by elemental analysis, FTIR, electronic spectra, magnetic moment and...
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Format: | Article |
Language: | English |
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College of science, university of Diyala
2025-01-01
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Series: | Academic Science Journal |
Online Access: | https://acadscij.uodiyala.edu.iq/index.php/Home/article/view/87 |
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author | Adel Salim Jinan Mohammed Mahmood Al-Zinkee Areej Ali Jarullah |
author_facet | Adel Salim Jinan Mohammed Mahmood Al-Zinkee Areej Ali Jarullah |
author_sort | Adel Salim |
collection | DOAJ |
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Complexes of Co(II), Ni(II), Cu(II) Zn(II), and Cd (II) with the ligand 3-(((2-amino-4-methylphenyl)imino)methyl)-4H-chromen-4-one derived 3-formyl chromone with 4-methyl-O-phenylenediamine were synthesized and characterized by elemental analysis, FTIR, electronic spectra, magnetic moment and molar conductance. The prepared complexes have the general formulae [M(C17H14N2O2)2]Cl2, M = Co(II), Ni(II), Cu(II) and Zn(II) except complex of cadmium it have the formulae [Cd(C17H14N2O2)Cl]Cl. The data which obtain from analysis indicate that the complexes have octahedral geometry around the metal center except cadmium complex exhibit tetrahedral geometry. Two types of bacteria (E.coli ) and (S. aureus ) used to estimate the biological activities of complexes .
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format | Article |
id | doaj-art-05c83a3f0a38407aaecb1307014d4813 |
institution | Kabale University |
issn | 2958-4612 2959-5568 |
language | English |
publishDate | 2025-01-01 |
publisher | College of science, university of Diyala |
record_format | Article |
series | Academic Science Journal |
spelling | doaj-art-05c83a3f0a38407aaecb1307014d48132025-02-04T04:26:34ZengCollege of science, university of DiyalaAcademic Science Journal2958-46122959-55682025-01-013110.24237/ASJ.03.01.753CSynthesis and biological evaluation for some metal complexes with a new ligand (E)-3-(((2-amino-4-methylphenyl)imino)methyl)-4H-chromen-4-oneAdel Salim0 Jinan Mohammed Mahmood Al-Zinkee1Areej Ali Jarullah2Diyala universityDepartment of Chemistry, College of Science, University of Diyala, Iraq.Department of Chemistry, College of Science, University of Diyala, Iraq. Complexes of Co(II), Ni(II), Cu(II) Zn(II), and Cd (II) with the ligand 3-(((2-amino-4-methylphenyl)imino)methyl)-4H-chromen-4-one derived 3-formyl chromone with 4-methyl-O-phenylenediamine were synthesized and characterized by elemental analysis, FTIR, electronic spectra, magnetic moment and molar conductance. The prepared complexes have the general formulae [M(C17H14N2O2)2]Cl2, M = Co(II), Ni(II), Cu(II) and Zn(II) except complex of cadmium it have the formulae [Cd(C17H14N2O2)Cl]Cl. The data which obtain from analysis indicate that the complexes have octahedral geometry around the metal center except cadmium complex exhibit tetrahedral geometry. Two types of bacteria (E.coli ) and (S. aureus ) used to estimate the biological activities of complexes . https://acadscij.uodiyala.edu.iq/index.php/Home/article/view/87 |
spellingShingle | Adel Salim Jinan Mohammed Mahmood Al-Zinkee Areej Ali Jarullah Synthesis and biological evaluation for some metal complexes with a new ligand (E)-3-(((2-amino-4-methylphenyl)imino)methyl)-4H-chromen-4-one Academic Science Journal |
title | Synthesis and biological evaluation for some metal complexes with a new ligand (E)-3-(((2-amino-4-methylphenyl)imino)methyl)-4H-chromen-4-one |
title_full | Synthesis and biological evaluation for some metal complexes with a new ligand (E)-3-(((2-amino-4-methylphenyl)imino)methyl)-4H-chromen-4-one |
title_fullStr | Synthesis and biological evaluation for some metal complexes with a new ligand (E)-3-(((2-amino-4-methylphenyl)imino)methyl)-4H-chromen-4-one |
title_full_unstemmed | Synthesis and biological evaluation for some metal complexes with a new ligand (E)-3-(((2-amino-4-methylphenyl)imino)methyl)-4H-chromen-4-one |
title_short | Synthesis and biological evaluation for some metal complexes with a new ligand (E)-3-(((2-amino-4-methylphenyl)imino)methyl)-4H-chromen-4-one |
title_sort | synthesis and biological evaluation for some metal complexes with a new ligand e 3 2 amino 4 methylphenyl imino methyl 4h chromen 4 one |
url | https://acadscij.uodiyala.edu.iq/index.php/Home/article/view/87 |
work_keys_str_mv | AT adelsalim synthesisandbiologicalevaluationforsomemetalcomplexeswithanewligande32amino4methylphenyliminomethyl4hchromen4one AT jinanmohammedmahmoodalzinkee synthesisandbiologicalevaluationforsomemetalcomplexeswithanewligande32amino4methylphenyliminomethyl4hchromen4one AT areejalijarullah synthesisandbiologicalevaluationforsomemetalcomplexeswithanewligande32amino4methylphenyliminomethyl4hchromen4one |