Synthesis and biological evaluation for some metal complexes with a new ligand (E)-3-(((2-amino-4-methylphenyl)imino)methyl)-4H-chromen-4-one

Complexes of Co(II),  Ni(II), Cu(II)  Zn(II),  and Cd (II) with the ligand 3-(((2-amino-4-methylphenyl)imino)methyl)-4H-chromen-4-one  derived 3-formyl chromone with 4-methyl-O-phenylenediamine were synthesized and characterized by elemental analysis, FTIR,  electronic spectra,  magnetic moment and...

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Main Authors: Adel Salim, Jinan Mohammed Mahmood Al-Zinkee, Areej Ali Jarullah
Format: Article
Language:English
Published: College of science, university of Diyala 2025-01-01
Series:Academic Science Journal
Online Access:https://acadscij.uodiyala.edu.iq/index.php/Home/article/view/87
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author Adel Salim
Jinan Mohammed Mahmood Al-Zinkee
Areej Ali Jarullah
author_facet Adel Salim
Jinan Mohammed Mahmood Al-Zinkee
Areej Ali Jarullah
author_sort Adel Salim
collection DOAJ
description Complexes of Co(II),  Ni(II), Cu(II)  Zn(II),  and Cd (II) with the ligand 3-(((2-amino-4-methylphenyl)imino)methyl)-4H-chromen-4-one  derived 3-formyl chromone with 4-methyl-O-phenylenediamine were synthesized and characterized by elemental analysis, FTIR,  electronic spectra,  magnetic moment and molar conductance. The prepared complexes have the general formulae [M(C17H14N2O2)2]Cl2, M = Co(II), Ni(II),  Cu(II) and  Zn(II) except complex of cadmium it have the formulae [Cd(C17H14N2O2)Cl]Cl.  The data which obtain from  analysis indicate  that  the complexes have octahedral geometry around the metal center except cadmium complex exhibit tetrahedral geometry. Two types of bacteria (E.coli ) and (S. aureus ) used to estimate the biological activities of complexes .
format Article
id doaj-art-05c83a3f0a38407aaecb1307014d4813
institution Kabale University
issn 2958-4612
2959-5568
language English
publishDate 2025-01-01
publisher College of science, university of Diyala
record_format Article
series Academic Science Journal
spelling doaj-art-05c83a3f0a38407aaecb1307014d48132025-02-04T04:26:34ZengCollege of science, university of DiyalaAcademic Science Journal2958-46122959-55682025-01-013110.24237/ASJ.03.01.753CSynthesis and biological evaluation for some metal complexes with a new ligand (E)-3-(((2-amino-4-methylphenyl)imino)methyl)-4H-chromen-4-oneAdel Salim0 Jinan Mohammed Mahmood Al-Zinkee1Areej Ali Jarullah2Diyala universityDepartment of Chemistry, College of Science, University of Diyala, Iraq.Department of Chemistry, College of Science, University of Diyala, Iraq. Complexes of Co(II),  Ni(II), Cu(II)  Zn(II),  and Cd (II) with the ligand 3-(((2-amino-4-methylphenyl)imino)methyl)-4H-chromen-4-one  derived 3-formyl chromone with 4-methyl-O-phenylenediamine were synthesized and characterized by elemental analysis, FTIR,  electronic spectra,  magnetic moment and molar conductance. The prepared complexes have the general formulae [M(C17H14N2O2)2]Cl2, M = Co(II), Ni(II),  Cu(II) and  Zn(II) except complex of cadmium it have the formulae [Cd(C17H14N2O2)Cl]Cl.  The data which obtain from  analysis indicate  that  the complexes have octahedral geometry around the metal center except cadmium complex exhibit tetrahedral geometry. Two types of bacteria (E.coli ) and (S. aureus ) used to estimate the biological activities of complexes . https://acadscij.uodiyala.edu.iq/index.php/Home/article/view/87
spellingShingle Adel Salim
Jinan Mohammed Mahmood Al-Zinkee
Areej Ali Jarullah
Synthesis and biological evaluation for some metal complexes with a new ligand (E)-3-(((2-amino-4-methylphenyl)imino)methyl)-4H-chromen-4-one
Academic Science Journal
title Synthesis and biological evaluation for some metal complexes with a new ligand (E)-3-(((2-amino-4-methylphenyl)imino)methyl)-4H-chromen-4-one
title_full Synthesis and biological evaluation for some metal complexes with a new ligand (E)-3-(((2-amino-4-methylphenyl)imino)methyl)-4H-chromen-4-one
title_fullStr Synthesis and biological evaluation for some metal complexes with a new ligand (E)-3-(((2-amino-4-methylphenyl)imino)methyl)-4H-chromen-4-one
title_full_unstemmed Synthesis and biological evaluation for some metal complexes with a new ligand (E)-3-(((2-amino-4-methylphenyl)imino)methyl)-4H-chromen-4-one
title_short Synthesis and biological evaluation for some metal complexes with a new ligand (E)-3-(((2-amino-4-methylphenyl)imino)methyl)-4H-chromen-4-one
title_sort synthesis and biological evaluation for some metal complexes with a new ligand e 3 2 amino 4 methylphenyl imino methyl 4h chromen 4 one
url https://acadscij.uodiyala.edu.iq/index.php/Home/article/view/87
work_keys_str_mv AT adelsalim synthesisandbiologicalevaluationforsomemetalcomplexeswithanewligande32amino4methylphenyliminomethyl4hchromen4one
AT jinanmohammedmahmoodalzinkee synthesisandbiologicalevaluationforsomemetalcomplexeswithanewligande32amino4methylphenyliminomethyl4hchromen4one
AT areejalijarullah synthesisandbiologicalevaluationforsomemetalcomplexeswithanewligande32amino4methylphenyliminomethyl4hchromen4one