Synthesis and Characterization of Novel Organo-Inorganic Hybrid Material of Poly(3,4-Ethylene Dioxythiophene) and Phosphomolybdate Anion

The organo-inorganic hybrid material, consisting of Poly(3,4-Ethylene Dioxythiophene) (PEDOT) doped with phosphomolybdate cluster anions [PMo12O40]3− , has been synthesized by direct in situ oxidative polymerization of 3,4-Ethylene Dioxythiophene (EDOT) with phosphomolybdic acid (H3PMo12O40) . Its c...

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Bibliographic Details
Main Authors: A. Vadivel Murugan, C.-W. Kwon, G. Campet, B. B. Kale
Format: Article
Language:English
Published: Wiley 2003-01-01
Series:Active and Passive Electronic Components
Online Access:http://dx.doi.org/10.1080/0882751031000073896
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Summary:The organo-inorganic hybrid material, consisting of Poly(3,4-Ethylene Dioxythiophene) (PEDOT) doped with phosphomolybdate cluster anions [PMo12O40]3− , has been synthesized by direct in situ oxidative polymerization of 3,4-Ethylene Dioxythiophene (EDOT) with phosphomolybdic acid (H3PMo12O40) . Its characterization is investigated by Fourier Transform Infrared Spectroscopy (FT-IR) and Scanning Electron Microscopy (SEM). The hybrid material presents predominantly high electronic conductivities of around 2.0 and 7.0 S cm-1 at 300 and 400K respectively.
ISSN:0882-7516
1563-5031