Synthesis, Crystal Structure, and DNA-Binding Studies of a Nickel(II) Complex with the Bis(2-benzimidazolymethyl)amine Ligand
A V-shaped ligand Bis(2-benzimidazolymethyl)amine (bba) and its nickel(II) picrate (pic) complex, with composition [Ni(bba)2](pic)2⋅3MeOH, have been synthesized and characterized on the basis of elemental analyses, molar conductivities, IR spectra, and UV/vis measurements. In the complex, the Ni(II)...
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| Format: | Article |
| Language: | English |
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Wiley
2012-01-01
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| Series: | Bioinorganic Chemistry and Applications |
| Online Access: | http://dx.doi.org/10.1155/2012/609796 |
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| author | Huilu Wu Tao Sun Ke Li Bin Liu Fan Kou Fei Jia Jingkun Yuan Ying Bai |
| author_facet | Huilu Wu Tao Sun Ke Li Bin Liu Fan Kou Fei Jia Jingkun Yuan Ying Bai |
| author_sort | Huilu Wu |
| collection | DOAJ |
| description | A V-shaped ligand Bis(2-benzimidazolymethyl)amine (bba) and its nickel(II) picrate (pic) complex, with composition [Ni(bba)2](pic)2⋅3MeOH, have been synthesized and characterized on the basis of elemental analyses, molar conductivities, IR spectra, and UV/vis measurements. In the complex, the Ni(II) ion is six-coordinated with a N2O4 ligand set, resulting in a distorted octahedron coordination geometry. In addition, the DNA-binding properties of the Ni(II) complex have been investigated by electronic absorption, fluorescence, and viscosity measurements. The experimental results suggest that the nickel(II) complex binds to DNA by partial intercalation binding mode. |
| format | Article |
| id | doaj-art-0558d39443f84b93bf7a7680b3dd3359 |
| institution | Kabale University |
| issn | 1565-3633 1687-479X |
| language | English |
| publishDate | 2012-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Bioinorganic Chemistry and Applications |
| spelling | doaj-art-0558d39443f84b93bf7a7680b3dd33592025-02-03T07:25:27ZengWileyBioinorganic Chemistry and Applications1565-36331687-479X2012-01-01201210.1155/2012/609796609796Synthesis, Crystal Structure, and DNA-Binding Studies of a Nickel(II) Complex with the Bis(2-benzimidazolymethyl)amine LigandHuilu Wu0Tao Sun1Ke Li2Bin Liu3Fan Kou4Fei Jia5Jingkun Yuan6Ying Bai7School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, ChinaSchool of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, ChinaSchool of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, ChinaSchool of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, ChinaSchool of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, ChinaSchool of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, ChinaSchool of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, ChinaSchool of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, ChinaA V-shaped ligand Bis(2-benzimidazolymethyl)amine (bba) and its nickel(II) picrate (pic) complex, with composition [Ni(bba)2](pic)2⋅3MeOH, have been synthesized and characterized on the basis of elemental analyses, molar conductivities, IR spectra, and UV/vis measurements. In the complex, the Ni(II) ion is six-coordinated with a N2O4 ligand set, resulting in a distorted octahedron coordination geometry. In addition, the DNA-binding properties of the Ni(II) complex have been investigated by electronic absorption, fluorescence, and viscosity measurements. The experimental results suggest that the nickel(II) complex binds to DNA by partial intercalation binding mode.http://dx.doi.org/10.1155/2012/609796 |
| spellingShingle | Huilu Wu Tao Sun Ke Li Bin Liu Fan Kou Fei Jia Jingkun Yuan Ying Bai Synthesis, Crystal Structure, and DNA-Binding Studies of a Nickel(II) Complex with the Bis(2-benzimidazolymethyl)amine Ligand Bioinorganic Chemistry and Applications |
| title | Synthesis, Crystal Structure, and DNA-Binding Studies of a Nickel(II) Complex with the Bis(2-benzimidazolymethyl)amine Ligand |
| title_full | Synthesis, Crystal Structure, and DNA-Binding Studies of a Nickel(II) Complex with the Bis(2-benzimidazolymethyl)amine Ligand |
| title_fullStr | Synthesis, Crystal Structure, and DNA-Binding Studies of a Nickel(II) Complex with the Bis(2-benzimidazolymethyl)amine Ligand |
| title_full_unstemmed | Synthesis, Crystal Structure, and DNA-Binding Studies of a Nickel(II) Complex with the Bis(2-benzimidazolymethyl)amine Ligand |
| title_short | Synthesis, Crystal Structure, and DNA-Binding Studies of a Nickel(II) Complex with the Bis(2-benzimidazolymethyl)amine Ligand |
| title_sort | synthesis crystal structure and dna binding studies of a nickel ii complex with the bis 2 benzimidazolymethyl amine ligand |
| url | http://dx.doi.org/10.1155/2012/609796 |
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