Energy of the So-called "Third Transition" and Intensity of Spin-forbidden Band in Chromium(III) complex of diethylamino-ethanethiol
The electronic spectra of chromium(III) complex of diethylamino-ethanethiol have been recorded. The value of Racah’s interelectronic repulsion parameter (B) has been evaluated and employed for the theoretical calculation of extra bands. The oscillator strength ratio of spin-forbidden to spin-allowe...
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| Format: | Article |
| Language: | deu |
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Swiss Chemical Society
1974-07-01
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| Series: | CHIMIA |
| Online Access: | https://www.chimia.ch/chimia/article/view/9147 |
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| _version_ | 1849311018131390464 |
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| author | P.C. Jain |
| author_facet | P.C. Jain |
| author_sort | P.C. Jain |
| collection | DOAJ |
| description |
The electronic spectra of chromium(III) complex of diethylamino-ethanethiol have been recorded. The value of Racah’s interelectronic repulsion parameter (B) has been evaluated and employed for the theoretical calculation of extra bands. The oscillator strength ratio of spin-forbidden to spin-allowed bands with “intensity stealing” has also been calculated.
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| format | Article |
| id | doaj-art-0500fd63c7884caa80afed30307f101e |
| institution | Kabale University |
| issn | 0009-4293 2673-2424 |
| language | deu |
| publishDate | 1974-07-01 |
| publisher | Swiss Chemical Society |
| record_format | Article |
| series | CHIMIA |
| spelling | doaj-art-0500fd63c7884caa80afed30307f101e2025-08-20T03:53:33ZdeuSwiss Chemical SocietyCHIMIA0009-42932673-24241974-07-0128710.2533/chimia.1974.340Energy of the So-called "Third Transition" and Intensity of Spin-forbidden Band in Chromium(III) complex of diethylamino-ethanethiolP.C. Jain0School of Chemistry, Meerut College, Meerut (India) The electronic spectra of chromium(III) complex of diethylamino-ethanethiol have been recorded. The value of Racah’s interelectronic repulsion parameter (B) has been evaluated and employed for the theoretical calculation of extra bands. The oscillator strength ratio of spin-forbidden to spin-allowed bands with “intensity stealing” has also been calculated. https://www.chimia.ch/chimia/article/view/9147 |
| spellingShingle | P.C. Jain Energy of the So-called "Third Transition" and Intensity of Spin-forbidden Band in Chromium(III) complex of diethylamino-ethanethiol CHIMIA |
| title | Energy of the So-called "Third Transition" and Intensity of Spin-forbidden Band in Chromium(III) complex of diethylamino-ethanethiol |
| title_full | Energy of the So-called "Third Transition" and Intensity of Spin-forbidden Band in Chromium(III) complex of diethylamino-ethanethiol |
| title_fullStr | Energy of the So-called "Third Transition" and Intensity of Spin-forbidden Band in Chromium(III) complex of diethylamino-ethanethiol |
| title_full_unstemmed | Energy of the So-called "Third Transition" and Intensity of Spin-forbidden Band in Chromium(III) complex of diethylamino-ethanethiol |
| title_short | Energy of the So-called "Third Transition" and Intensity of Spin-forbidden Band in Chromium(III) complex of diethylamino-ethanethiol |
| title_sort | energy of the so called third transition and intensity of spin forbidden band in chromium iii complex of diethylamino ethanethiol |
| url | https://www.chimia.ch/chimia/article/view/9147 |
| work_keys_str_mv | AT pcjain energyofthesocalledthirdtransitionandintensityofspinforbiddenbandinchromiumiiicomplexofdiethylaminoethanethiol |