Energy of the So-called "Third Transition" and Intensity of Spin-forbidden Band in Chromium(III) complex of diethylamino-ethanethiol
The electronic spectra of chromium(III) complex of diethylamino-ethanethiol have been recorded. The value of Racah’s interelectronic repulsion parameter (B) has been evaluated and employed for the theoretical calculation of extra bands. The oscillator strength ratio of spin-forbidden to spin-allowe...
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| Format: | Article |
| Language: | deu |
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Swiss Chemical Society
1974-07-01
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| Series: | CHIMIA |
| Online Access: | https://www.chimia.ch/chimia/article/view/9147 |
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| Summary: | The electronic spectra of chromium(III) complex of diethylamino-ethanethiol have been recorded. The value of Racah’s interelectronic repulsion parameter (B) has been evaluated and employed for the theoretical calculation of extra bands. The oscillator strength ratio of spin-forbidden to spin-allowed bands with “intensity stealing” has also been calculated.
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| ISSN: | 0009-4293 2673-2424 |