Electrospinning of annatto-loaded cellulose acetate scaffolds using acetone/DMSO as solvent

Electrospinning has emerged as a versatile technique for producing nanofibers for diverse applications. The fibers produced are highly regarded for their biocompatibility, exceptional surface-to-volume ratios, porosity, and adjustable composition properties, making them promising scaffolds for tissu...

Full description

Saved in:
Bibliographic Details
Main Authors: Dreier Tim, Neukirch Florian, Priebe Hannes, Seitz Hermann
Format: Article
Language:English
Published: De Gruyter 2024-12-01
Series:Current Directions in Biomedical Engineering
Subjects:
Online Access:https://doi.org/10.1515/cdbme-2024-2050
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1850032069187469312
author Dreier Tim
Neukirch Florian
Priebe Hannes
Seitz Hermann
author_facet Dreier Tim
Neukirch Florian
Priebe Hannes
Seitz Hermann
author_sort Dreier Tim
collection DOAJ
description Electrospinning has emerged as a versatile technique for producing nanofibers for diverse applications. The fibers produced are highly regarded for their biocompatibility, exceptional surface-to-volume ratios, porosity, and adjustable composition properties, making them promising scaffolds for tissue engineering. In the literature, annatto-loaded cellulose acetate has already been successfully used for electrospinning. However, N,N-dimethylformamide (DMF) was utilized as a solvent in the experiments, which is considered a carcinogenic and mutagenic substance. The aim of this study is to analyze whether comparable results can be achieved with a low toxicity solvent consisting of acetone and dimethyl sulfoxide (DMSO). In this study, we investigate the electrospinning process of cellulose acetate (CA) and cellulose acetate combined with annatto extract (CA/A). Initially, various polymer concentrations ranging from 12% to 16% (w/v) were characterized by rheological measurements to determine their suitability for electrospinning. The morphology and diameter distribution of the electrospun fibers were analyzed using scanning electron microscopy (SEM). Contact angle measurements were carried out to determine the wettability of the electrospun meshes. The rheological investigations conducted revealed that increasing the polymer content of CA raises viscosity, while the incorporation of annatto decreases it. Uniform fibers are achieved at polymer concentrations of 14% and above. The electrospun nanofibers exhibit uniform morphology and diameters in the nanometer range, indicating the successful fabrication of annatto-loaded CA nanofibers. The contact angle measurements showed hydrophilic behavior on all investigated meshes. The incorporation of annatto extract in the electrospun fibers holds promise for various applications, including biomedical scaffolds, scaffolds for cultured meat, filtration membranes and food packaging materials. This study provides valuable insights into optimizing electrospinning parameters for the fabrication of functional nanofibers with enhanced properties.
format Article
id doaj-art-04d3b37d6ea0464a97f8302f117bf6ed
institution DOAJ
issn 2364-5504
language English
publishDate 2024-12-01
publisher De Gruyter
record_format Article
series Current Directions in Biomedical Engineering
spelling doaj-art-04d3b37d6ea0464a97f8302f117bf6ed2025-08-20T02:58:46ZengDe GruyterCurrent Directions in Biomedical Engineering2364-55042024-12-0110420821110.1515/cdbme-2024-2050Electrospinning of annatto-loaded cellulose acetate scaffolds using acetone/DMSO as solventDreier Tim0Neukirch Florian1Priebe Hannes2Seitz Hermann3Chair of Microfluidics, University of Rostock, Justus-von-Liebig-Weg 6, 18059Rostock, GermanyChair of Microfluidics, University of Rostock, Justus-von-Liebig-Weg 6, 18059Rostock, GermanyChair of Microfluidics, University of Rostock, Justus-von-Liebig-Weg 6, 18059Rostock, GermanyChair of Microfluidics, University of Rostock, Justus-von-Liebig-Weg 6, 18059Rostock, GermanyElectrospinning has emerged as a versatile technique for producing nanofibers for diverse applications. The fibers produced are highly regarded for their biocompatibility, exceptional surface-to-volume ratios, porosity, and adjustable composition properties, making them promising scaffolds for tissue engineering. In the literature, annatto-loaded cellulose acetate has already been successfully used for electrospinning. However, N,N-dimethylformamide (DMF) was utilized as a solvent in the experiments, which is considered a carcinogenic and mutagenic substance. The aim of this study is to analyze whether comparable results can be achieved with a low toxicity solvent consisting of acetone and dimethyl sulfoxide (DMSO). In this study, we investigate the electrospinning process of cellulose acetate (CA) and cellulose acetate combined with annatto extract (CA/A). Initially, various polymer concentrations ranging from 12% to 16% (w/v) were characterized by rheological measurements to determine their suitability for electrospinning. The morphology and diameter distribution of the electrospun fibers were analyzed using scanning electron microscopy (SEM). Contact angle measurements were carried out to determine the wettability of the electrospun meshes. The rheological investigations conducted revealed that increasing the polymer content of CA raises viscosity, while the incorporation of annatto decreases it. Uniform fibers are achieved at polymer concentrations of 14% and above. The electrospun nanofibers exhibit uniform morphology and diameters in the nanometer range, indicating the successful fabrication of annatto-loaded CA nanofibers. The contact angle measurements showed hydrophilic behavior on all investigated meshes. The incorporation of annatto extract in the electrospun fibers holds promise for various applications, including biomedical scaffolds, scaffolds for cultured meat, filtration membranes and food packaging materials. This study provides valuable insights into optimizing electrospinning parameters for the fabrication of functional nanofibers with enhanced properties.https://doi.org/10.1515/cdbme-2024-2050electrospinningscaffoldscellulose acetateannattoacetone/dmso
spellingShingle Dreier Tim
Neukirch Florian
Priebe Hannes
Seitz Hermann
Electrospinning of annatto-loaded cellulose acetate scaffolds using acetone/DMSO as solvent
Current Directions in Biomedical Engineering
electrospinning
scaffolds
cellulose acetate
annatto
acetone/dmso
title Electrospinning of annatto-loaded cellulose acetate scaffolds using acetone/DMSO as solvent
title_full Electrospinning of annatto-loaded cellulose acetate scaffolds using acetone/DMSO as solvent
title_fullStr Electrospinning of annatto-loaded cellulose acetate scaffolds using acetone/DMSO as solvent
title_full_unstemmed Electrospinning of annatto-loaded cellulose acetate scaffolds using acetone/DMSO as solvent
title_short Electrospinning of annatto-loaded cellulose acetate scaffolds using acetone/DMSO as solvent
title_sort electrospinning of annatto loaded cellulose acetate scaffolds using acetone dmso as solvent
topic electrospinning
scaffolds
cellulose acetate
annatto
acetone/dmso
url https://doi.org/10.1515/cdbme-2024-2050
work_keys_str_mv AT dreiertim electrospinningofannattoloadedcelluloseacetatescaffoldsusingacetonedmsoassolvent
AT neukirchflorian electrospinningofannattoloadedcelluloseacetatescaffoldsusingacetonedmsoassolvent
AT priebehannes electrospinningofannattoloadedcelluloseacetatescaffoldsusingacetonedmsoassolvent
AT seitzhermann electrospinningofannattoloadedcelluloseacetatescaffoldsusingacetonedmsoassolvent