Quantify typical trapping sites of deuterium in tungsten by sequential thermal desorption coupled with a dedicated numerical diffusion model

Pure tungsten (W) was irradiated by low-energy deuterium (D) at 335 and 500 K to investigate the effects of irradiation temperature on the concentration depth profiles (CDPs) of D-induced trapping sites and the retention behavior of D at these trapping sites. To quantify typical D trapping sites, a...

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Main Authors: Lin-Ping He, Cong Li, Jie Gao, Wei Zhang, Li-Qun Shi, Hong-Liang Zhang
Format: Article
Language:English
Published: IOP Publishing 2024-01-01
Series:Nuclear Fusion
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Online Access:https://doi.org/10.1088/1741-4326/ad9ab8
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author Lin-Ping He
Cong Li
Jie Gao
Wei Zhang
Li-Qun Shi
Hong-Liang Zhang
author_facet Lin-Ping He
Cong Li
Jie Gao
Wei Zhang
Li-Qun Shi
Hong-Liang Zhang
author_sort Lin-Ping He
collection DOAJ
description Pure tungsten (W) was irradiated by low-energy deuterium (D) at 335 and 500 K to investigate the effects of irradiation temperature on the concentration depth profiles (CDPs) of D-induced trapping sites and the retention behavior of D at these trapping sites. To quantify typical D trapping sites, a novel approach was developed by combining experimental and theoretical analysis, including the sequential constant temperature thermal desorption to fast release D from irradiated W, in-situ ion beam analysis to obtain CDPs of retained D after desorption, and a one-dimensional diffusion model to simulate the diffusion, trapping and detrapping of D during desorption. The approach was verified through the microstructural characterization of irradiated W. It was revealed that the retentions of D in both near-surface and sub-surface layers were larger at the lower irradiation temperature (335 K) because of a higher density of D-induced dislocations and cavities in the corresponding regions. Employing the approach, the releasing behavior of D at four typical trapping sites, i.e. dislocations, mono-vacancies, grain boundaries and cavities was quantitatively analyzed. The approach with the capability to quantify typical D trapping sites provides a powerful tool for understanding the retention mechanism of D in the damaged W.
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issn 0029-5515
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publisher IOP Publishing
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series Nuclear Fusion
spelling doaj-art-04989a740ff548d38879b7dfd8161ec42025-08-20T02:28:55ZengIOP PublishingNuclear Fusion0029-55152024-01-0165101605610.1088/1741-4326/ad9ab8Quantify typical trapping sites of deuterium in tungsten by sequential thermal desorption coupled with a dedicated numerical diffusion modelLin-Ping He0Cong Li1Jie Gao2https://orcid.org/0000-0002-4321-4063Wei Zhang3Li-Qun Shi4Hong-Liang Zhang5Key Laboratory of Nuclear Physics and Ion-Beam Application, Institute of Modern Physics, Fudan University , Shanghai 200433, ChinaKey Laboratory of Nuclear Physics and Ion-Beam Application, Institute of Modern Physics, Fudan University , Shanghai 200433, China; Shanghai Institute of Applied Physics, Chinese Academy of Sciences , Shanghai 201800, ChinaKey Laboratory of Nuclear Physics and Ion-Beam Application, Institute of Modern Physics, Fudan University , Shanghai 200433, ChinaKey Laboratory of Nuclear Physics and Ion-Beam Application, Institute of Modern Physics, Fudan University , Shanghai 200433, ChinaKey Laboratory of Nuclear Physics and Ion-Beam Application, Institute of Modern Physics, Fudan University , Shanghai 200433, ChinaKey Laboratory of Nuclear Physics and Ion-Beam Application, Institute of Modern Physics, Fudan University , Shanghai 200433, ChinaPure tungsten (W) was irradiated by low-energy deuterium (D) at 335 and 500 K to investigate the effects of irradiation temperature on the concentration depth profiles (CDPs) of D-induced trapping sites and the retention behavior of D at these trapping sites. To quantify typical D trapping sites, a novel approach was developed by combining experimental and theoretical analysis, including the sequential constant temperature thermal desorption to fast release D from irradiated W, in-situ ion beam analysis to obtain CDPs of retained D after desorption, and a one-dimensional diffusion model to simulate the diffusion, trapping and detrapping of D during desorption. The approach was verified through the microstructural characterization of irradiated W. It was revealed that the retentions of D in both near-surface and sub-surface layers were larger at the lower irradiation temperature (335 K) because of a higher density of D-induced dislocations and cavities in the corresponding regions. Employing the approach, the releasing behavior of D at four typical trapping sites, i.e. dislocations, mono-vacancies, grain boundaries and cavities was quantitatively analyzed. The approach with the capability to quantify typical D trapping sites provides a powerful tool for understanding the retention mechanism of D in the damaged W.https://doi.org/10.1088/1741-4326/ad9ab8low-energy D irradiationtrapping sitesconcentration depth profilesconstant temperature thermal desorptionone-dimensional diffusion model
spellingShingle Lin-Ping He
Cong Li
Jie Gao
Wei Zhang
Li-Qun Shi
Hong-Liang Zhang
Quantify typical trapping sites of deuterium in tungsten by sequential thermal desorption coupled with a dedicated numerical diffusion model
Nuclear Fusion
low-energy D irradiation
trapping sites
concentration depth profiles
constant temperature thermal desorption
one-dimensional diffusion model
title Quantify typical trapping sites of deuterium in tungsten by sequential thermal desorption coupled with a dedicated numerical diffusion model
title_full Quantify typical trapping sites of deuterium in tungsten by sequential thermal desorption coupled with a dedicated numerical diffusion model
title_fullStr Quantify typical trapping sites of deuterium in tungsten by sequential thermal desorption coupled with a dedicated numerical diffusion model
title_full_unstemmed Quantify typical trapping sites of deuterium in tungsten by sequential thermal desorption coupled with a dedicated numerical diffusion model
title_short Quantify typical trapping sites of deuterium in tungsten by sequential thermal desorption coupled with a dedicated numerical diffusion model
title_sort quantify typical trapping sites of deuterium in tungsten by sequential thermal desorption coupled with a dedicated numerical diffusion model
topic low-energy D irradiation
trapping sites
concentration depth profiles
constant temperature thermal desorption
one-dimensional diffusion model
url https://doi.org/10.1088/1741-4326/ad9ab8
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