Characteristics of genetic mineralogy of pyrite and quartz and their indicating significance in the Gaosongshan Gold Deposit, Heilongjiang Province, NE China

The Gaosongshan epithermal gold deposit in Heilongjiang, Northeast China, is hosted by the Lower Cretaceous intermediate-basic volcanic rocks. Three auriferous quartz veins including eleven gold orebodies were all discovered in tectonoclastic zones. Genetic mineralogy study including the thermoelect...

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Main Authors: Huiqing Geng, Xuexiang Gu, Yongmei Zhang
Format: Article
Language:English
Published: Universidad Nacional de Colombia 2018-10-01
Series:Earth Sciences Research Journal
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Online Access:https://revistas.unal.edu.co/index.php/esrj/article/view/57512
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author Huiqing Geng
Xuexiang Gu
Yongmei Zhang
author_facet Huiqing Geng
Xuexiang Gu
Yongmei Zhang
author_sort Huiqing Geng
collection DOAJ
description The Gaosongshan epithermal gold deposit in Heilongjiang, Northeast China, is hosted by the Lower Cretaceous intermediate-basic volcanic rocks. Three auriferous quartz veins including eleven gold orebodies were all discovered in tectonoclastic zones. Genetic mineralogy study including the thermoelectricity, rare earth elements and trace elements of pyrite and rare earth elements of quartz were carried out. Thermoelectric conductive type of pyrite is mainly N-P type. Calculating the thermoelectric parameters XNP and denudation percentage γ of pyrites from orebodies 1-I, 2-II and 2-IV, suggests that gold orebodies are all eroded to their middle-lower parts. The variable range of Co concentrations (51.3-264.0ppm) and Ni concentrations (68.9-258.0ppm) and Co: Ni ratio (0.31-1.90), together with relatively small Sr/Ba ratio in ore-bearing pyrites (0.11-0.50), supports a hydrothermal origin of mineralization at Gaosongshan gold deposit. Compared with volcanic rocks, the chondrite-normalized REE patterns of ore-bearing pyrites and quartz are all LREE enriched with similar ΣLREE/ΣHREE ratio ranging from 7.37-13.68 in ore-bearing pyrites, 4.74-15.37 in ore-bearing quartz and no Ce anomalies. δEu values in ore-bearing pyrites and quartz are 0.65-1.66 (average=0.93) and 0.66-1.62 (average=1.03), respectively. δEu values of volcanic rocks are 0.86­1.07 (average 0.94), suggesting no obvious negative Eu anomalies. Similar REE characteristics of ore-bearing pyrites and quartz and volcanic rocks, together with previous oxygen and hydrogen isotope studies of quartz, suggest that the ore-forming fluids of the Gaosongshan gold deposit were mainly magmatic origin which was associated with andesitic magma and was partly mixed with atmospheric water. Comparing trace elements characteristics of ore-bearing pyrites with volcanic rocks, together with previous S isotopic studies, it is concluded that the ore-forming materials were derived from the surrounding rocks. Slight changes of Y/Ho (23.80­27.28), Zr/Hf (35.41­47.83), Nb/Ta (10.96­18.52) in ore-bearing pyrites indicate that the ore-forming fluid system is relatively stable during the ore-forming process.
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spelling doaj-art-047e4fee199b4a5c81d1cee6a3a3ae102025-08-20T02:19:15ZengUniversidad Nacional de ColombiaEarth Sciences Research Journal1794-61902339-34592018-10-0122430131810.15446/esrj.v22n4.5751250243Characteristics of genetic mineralogy of pyrite and quartz and their indicating significance in the Gaosongshan Gold Deposit, Heilongjiang Province, NE ChinaHuiqing Geng0Xuexiang Gu1Yongmei Zhang2China University of GeosciencesChina University of GeosciencesChina University of GeosciencesThe Gaosongshan epithermal gold deposit in Heilongjiang, Northeast China, is hosted by the Lower Cretaceous intermediate-basic volcanic rocks. Three auriferous quartz veins including eleven gold orebodies were all discovered in tectonoclastic zones. Genetic mineralogy study including the thermoelectricity, rare earth elements and trace elements of pyrite and rare earth elements of quartz were carried out. Thermoelectric conductive type of pyrite is mainly N-P type. Calculating the thermoelectric parameters XNP and denudation percentage γ of pyrites from orebodies 1-I, 2-II and 2-IV, suggests that gold orebodies are all eroded to their middle-lower parts. The variable range of Co concentrations (51.3-264.0ppm) and Ni concentrations (68.9-258.0ppm) and Co: Ni ratio (0.31-1.90), together with relatively small Sr/Ba ratio in ore-bearing pyrites (0.11-0.50), supports a hydrothermal origin of mineralization at Gaosongshan gold deposit. Compared with volcanic rocks, the chondrite-normalized REE patterns of ore-bearing pyrites and quartz are all LREE enriched with similar ΣLREE/ΣHREE ratio ranging from 7.37-13.68 in ore-bearing pyrites, 4.74-15.37 in ore-bearing quartz and no Ce anomalies. δEu values in ore-bearing pyrites and quartz are 0.65-1.66 (average=0.93) and 0.66-1.62 (average=1.03), respectively. δEu values of volcanic rocks are 0.86­1.07 (average 0.94), suggesting no obvious negative Eu anomalies. Similar REE characteristics of ore-bearing pyrites and quartz and volcanic rocks, together with previous oxygen and hydrogen isotope studies of quartz, suggest that the ore-forming fluids of the Gaosongshan gold deposit were mainly magmatic origin which was associated with andesitic magma and was partly mixed with atmospheric water. Comparing trace elements characteristics of ore-bearing pyrites with volcanic rocks, together with previous S isotopic studies, it is concluded that the ore-forming materials were derived from the surrounding rocks. Slight changes of Y/Ho (23.80­27.28), Zr/Hf (35.41­47.83), Nb/Ta (10.96­18.52) in ore-bearing pyrites indicate that the ore-forming fluid system is relatively stable during the ore-forming process.https://revistas.unal.edu.co/index.php/esrj/article/view/57512PyriteQuartzRare earth elementsGenetic MineralogyGaosongshan Gold DepositChina
spellingShingle Huiqing Geng
Xuexiang Gu
Yongmei Zhang
Characteristics of genetic mineralogy of pyrite and quartz and their indicating significance in the Gaosongshan Gold Deposit, Heilongjiang Province, NE China
Earth Sciences Research Journal
Pyrite
Quartz
Rare earth elements
Genetic Mineralogy
Gaosongshan Gold Deposit
China
title Characteristics of genetic mineralogy of pyrite and quartz and their indicating significance in the Gaosongshan Gold Deposit, Heilongjiang Province, NE China
title_full Characteristics of genetic mineralogy of pyrite and quartz and their indicating significance in the Gaosongshan Gold Deposit, Heilongjiang Province, NE China
title_fullStr Characteristics of genetic mineralogy of pyrite and quartz and their indicating significance in the Gaosongshan Gold Deposit, Heilongjiang Province, NE China
title_full_unstemmed Characteristics of genetic mineralogy of pyrite and quartz and their indicating significance in the Gaosongshan Gold Deposit, Heilongjiang Province, NE China
title_short Characteristics of genetic mineralogy of pyrite and quartz and their indicating significance in the Gaosongshan Gold Deposit, Heilongjiang Province, NE China
title_sort characteristics of genetic mineralogy of pyrite and quartz and their indicating significance in the gaosongshan gold deposit heilongjiang province ne china
topic Pyrite
Quartz
Rare earth elements
Genetic Mineralogy
Gaosongshan Gold Deposit
China
url https://revistas.unal.edu.co/index.php/esrj/article/view/57512
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