Mechanical Tensile Response of Ni–Graphene Nanocomposites in Hydrogen-Irradiation-Coupled Environments Using Molecular Dynamics Simulations

In Gen-IV nuclear reactors, structural materials must endure unprecedented levels of neutron irradiation and hydrogen exposure, posing significant challenges for traditional Ni-based alloys. This study evaluates Ni–graphene nanocomposites (NGNCs) as a promising solution, leveraging their inherent ra...

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Main Authors: Tonghe Liu, Xiaoting Yuan, Hai Huang
Format: Article
Language:English
Published: MDPI AG 2025-06-01
Series:Nanomaterials
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Online Access:https://www.mdpi.com/2079-4991/15/13/970
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author Tonghe Liu
Xiaoting Yuan
Hai Huang
author_facet Tonghe Liu
Xiaoting Yuan
Hai Huang
author_sort Tonghe Liu
collection DOAJ
description In Gen-IV nuclear reactors, structural materials must endure unprecedented levels of neutron irradiation and hydrogen exposure, posing significant challenges for traditional Ni-based alloys. This study evaluates Ni–graphene nanocomposites (NGNCs) as a promising solution, leveraging their inherent radiation tolerance and hydrogen diffusion suppression. Using molecular dynamics simulations, we investigate how Ni/graphene interfaces influence mechanical properties under combined hydrogen permeation and displacement damage. Key parameters, such as hydrogen concentration, displacement damage level, strain rate, and temperature, are systematically varied to assess their impact on stress–strain behavior (including Young’s modulus and tensile strength), with comparisons to single-crystal nickel. Our findings reveal that NGNCs exhibit distinct mechanical responses characterized by serrated stress–strain curves due to interfacial slip. Hydrogen and irradiation effects are complex: low hydrogen levels can increase Young’s modulus, while higher concentrations and irradiation generally degrade strength, with NGNCs being more affected than single-crystal nickel. Additionally, NGNCs show enhanced thermal stability but increased strain rate sensitivity. These results provide critical insights for designing materials that balance reinforcement with environmental resilience in nuclear applications.
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spelling doaj-art-045b7e338ea1427a987d9e7d3bae6e622025-08-20T03:16:42ZengMDPI AGNanomaterials2079-49912025-06-01151397010.3390/nano15130970Mechanical Tensile Response of Ni–Graphene Nanocomposites in Hydrogen-Irradiation-Coupled Environments Using Molecular Dynamics SimulationsTonghe Liu0Xiaoting Yuan1Hai Huang2Key Laboratory of Material Physics, Ministry of Education, School of Physics, Zhengzhou University, Zhengzhou 450001, ChinaKey Laboratory of Material Physics, Ministry of Education, School of Physics, Zhengzhou University, Zhengzhou 450001, ChinaKey Laboratory of Material Physics, Ministry of Education, School of Physics, Zhengzhou University, Zhengzhou 450001, ChinaIn Gen-IV nuclear reactors, structural materials must endure unprecedented levels of neutron irradiation and hydrogen exposure, posing significant challenges for traditional Ni-based alloys. This study evaluates Ni–graphene nanocomposites (NGNCs) as a promising solution, leveraging their inherent radiation tolerance and hydrogen diffusion suppression. Using molecular dynamics simulations, we investigate how Ni/graphene interfaces influence mechanical properties under combined hydrogen permeation and displacement damage. Key parameters, such as hydrogen concentration, displacement damage level, strain rate, and temperature, are systematically varied to assess their impact on stress–strain behavior (including Young’s modulus and tensile strength), with comparisons to single-crystal nickel. Our findings reveal that NGNCs exhibit distinct mechanical responses characterized by serrated stress–strain curves due to interfacial slip. Hydrogen and irradiation effects are complex: low hydrogen levels can increase Young’s modulus, while higher concentrations and irradiation generally degrade strength, with NGNCs being more affected than single-crystal nickel. Additionally, NGNCs show enhanced thermal stability but increased strain rate sensitivity. These results provide critical insights for designing materials that balance reinforcement with environmental resilience in nuclear applications.https://www.mdpi.com/2079-4991/15/13/970Ni–graphene nanocompositesmechanical responsehydrogen exposuredisplacement damageradiation tolerance
spellingShingle Tonghe Liu
Xiaoting Yuan
Hai Huang
Mechanical Tensile Response of Ni–Graphene Nanocomposites in Hydrogen-Irradiation-Coupled Environments Using Molecular Dynamics Simulations
Nanomaterials
Ni–graphene nanocomposites
mechanical response
hydrogen exposure
displacement damage
radiation tolerance
title Mechanical Tensile Response of Ni–Graphene Nanocomposites in Hydrogen-Irradiation-Coupled Environments Using Molecular Dynamics Simulations
title_full Mechanical Tensile Response of Ni–Graphene Nanocomposites in Hydrogen-Irradiation-Coupled Environments Using Molecular Dynamics Simulations
title_fullStr Mechanical Tensile Response of Ni–Graphene Nanocomposites in Hydrogen-Irradiation-Coupled Environments Using Molecular Dynamics Simulations
title_full_unstemmed Mechanical Tensile Response of Ni–Graphene Nanocomposites in Hydrogen-Irradiation-Coupled Environments Using Molecular Dynamics Simulations
title_short Mechanical Tensile Response of Ni–Graphene Nanocomposites in Hydrogen-Irradiation-Coupled Environments Using Molecular Dynamics Simulations
title_sort mechanical tensile response of ni graphene nanocomposites in hydrogen irradiation coupled environments using molecular dynamics simulations
topic Ni–graphene nanocomposites
mechanical response
hydrogen exposure
displacement damage
radiation tolerance
url https://www.mdpi.com/2079-4991/15/13/970
work_keys_str_mv AT tongheliu mechanicaltensileresponseofnigraphenenanocompositesinhydrogenirradiationcoupledenvironmentsusingmoleculardynamicssimulations
AT xiaotingyuan mechanicaltensileresponseofnigraphenenanocompositesinhydrogenirradiationcoupledenvironmentsusingmoleculardynamicssimulations
AT haihuang mechanicaltensileresponseofnigraphenenanocompositesinhydrogenirradiationcoupledenvironmentsusingmoleculardynamicssimulations