A new generation of ecocatalysts$^{\text{®}}$—from Invasive Alien Species to sustainable and biosourced glyceryl fatty esters
A new generation of ecocatalysts$^{\text{®}}$ derived from Invasive Alien Species (IAS) (Fallopia japonica and Arundo donax) was used as starting material for the preparation of novel biosourced catalysts. The preparation of these ecocatalysts$^{\text{®}}$ is a new way to support the management of I...
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| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Académie des sciences
2024-03-01
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| Series: | Comptes Rendus. Chimie |
| Subjects: | |
| Online Access: | https://comptes-rendus.academie-sciences.fr/chimie/articles/10.5802/crchim.273/ |
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| Summary: | A new generation of ecocatalysts$^{\text{®}}$ derived from Invasive Alien Species (IAS) (Fallopia japonica and Arundo donax) was used as starting material for the preparation of novel biosourced catalysts. The preparation of these ecocatalysts$^{\text{®}}$ is a new way to support the management of IAS. These catalysts were characterized by microwave plasma atomic emission spectrometry (MP-AES) and X-ray powder diffraction (XRPD), which revealed basic properties. After calculating Pearson’s correlations to evaluate the relative importance of reaction parameters, a design of experiments (DoE) was implemented to synthesize glyceryl caprylate and oleate with a high selectivity. These molecules constitute emollients and non-ionic emulsifiers of high industrial interest. The ecocatalysts$^{\text{®}}$ were efficient and recyclable for the transesterification of methyl and ethyl fatty esters, leading to high yields (66–83%). These ecocatalysts$^{\text{®}}$ are an alternative to usual base catalysts previously reported for the transesterification of methyl caprylate, methyl oleate and ethyl caprylate with glycerol, which are often non-recyclable, not systematically selective and require questionable preparation conditions. |
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| ISSN: | 1878-1543 |