Process tensor approaches to modeling two-dimensional spectroscopy

Problems in the field of open quantum systems often involve an environment that strongly influences the dynamics of excited states. Here we present a numerical method to model optical spectra of non-Markovian open quantum systems. The method employs a process tensor framework to efficiently compute...

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Main Authors: Roosmarijn de Wit, Jonathan Keeling, Brendon W. Lovett, Alex W. Chin
Format: Article
Language:English
Published: American Physical Society 2025-02-01
Series:Physical Review Research
Online Access:http://doi.org/10.1103/PhysRevResearch.7.013209
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author Roosmarijn de Wit
Jonathan Keeling
Brendon W. Lovett
Alex W. Chin
author_facet Roosmarijn de Wit
Jonathan Keeling
Brendon W. Lovett
Alex W. Chin
author_sort Roosmarijn de Wit
collection DOAJ
description Problems in the field of open quantum systems often involve an environment that strongly influences the dynamics of excited states. Here we present a numerical method to model optical spectra of non-Markovian open quantum systems. The method employs a process tensor framework to efficiently compute multitime correlations in a numerically exact way. To demonstrate the efficacy of our method, we compare 2D electronic spectroscopy simulations produced through our method to Markovian master equation simulations in three different system-bath coupling regimes.
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spelling doaj-art-04069124e5694ca09509f546e002fcdc2025-08-20T02:04:18ZengAmerican Physical SocietyPhysical Review Research2643-15642025-02-017101320910.1103/PhysRevResearch.7.013209Process tensor approaches to modeling two-dimensional spectroscopyRoosmarijn de WitJonathan KeelingBrendon W. LovettAlex W. ChinProblems in the field of open quantum systems often involve an environment that strongly influences the dynamics of excited states. Here we present a numerical method to model optical spectra of non-Markovian open quantum systems. The method employs a process tensor framework to efficiently compute multitime correlations in a numerically exact way. To demonstrate the efficacy of our method, we compare 2D electronic spectroscopy simulations produced through our method to Markovian master equation simulations in three different system-bath coupling regimes.http://doi.org/10.1103/PhysRevResearch.7.013209
spellingShingle Roosmarijn de Wit
Jonathan Keeling
Brendon W. Lovett
Alex W. Chin
Process tensor approaches to modeling two-dimensional spectroscopy
Physical Review Research
title Process tensor approaches to modeling two-dimensional spectroscopy
title_full Process tensor approaches to modeling two-dimensional spectroscopy
title_fullStr Process tensor approaches to modeling two-dimensional spectroscopy
title_full_unstemmed Process tensor approaches to modeling two-dimensional spectroscopy
title_short Process tensor approaches to modeling two-dimensional spectroscopy
title_sort process tensor approaches to modeling two dimensional spectroscopy
url http://doi.org/10.1103/PhysRevResearch.7.013209
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