Ion-exchange adsorption processes in hydrostratisphere

On the basis of field and experimental lithological and hydrochemical investigations carried out in the Volga-Ural sedimentary basin, a number of important provisions related to the mechanism and kinetics of cation exchange in a heterogeneous system of water-rock have been done. It has been establis...

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Main Authors: V. G. Popov, R. F. Abdrahmanov
Format: Article
Language:Russian
Published: Sergo Ordzhonikidze Russian State University for Geological Prospecting 2016-02-01
Series:Известия высших учебных заведений: Геология и разведка
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Online Access:https://www.geology-mgri.ru/jour/article/view/110
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author V. G. Popov
R. F. Abdrahmanov
author_facet V. G. Popov
R. F. Abdrahmanov
author_sort V. G. Popov
collection DOAJ
description On the basis of field and experimental lithological and hydrochemical investigations carried out in the Volga-Ural sedimentary basin, a number of important provisions related to the mechanism and kinetics of cation exchange in a heterogeneous system of water-rock have been done. It has been established that they are zonal and differentiated by the depth of the basin. The most significant ion-exchange interaction is in the top of the supergene zone (up to 300 m) with Upper Permian argillaceous sediments with high adsorption properties. Here a radical metamorphic composition of underground fluids and formation of fresh sodium bicarbonate and sodium sulfate salty waters are marked. In areas of catagenesis and metagenesis at the depths greater than 1000-1500 m as a result of the restructuring of the clay minerals in the series of montmorillonite-hydromica-chlorite, the absorption capacity of the adsorption complex of clastic formations of Paleozoic and Late Proterozoic is sharply reduced. Exchange adsorption loses its geochemical significance and plays no significant role in the formation of calcium chloride brines. Their origin is associated with the processes of epigenetic dolomitization of limestone under the influence of density convection of the sodium chloride and magnesium brines from the Permian evaporate paleobasins.
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publishDate 2016-02-01
publisher Sergo Ordzhonikidze Russian State University for Geological Prospecting
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series Известия высших учебных заведений: Геология и разведка
spelling doaj-art-03fd457a84144649962dd6d9bb60f7df2025-08-20T03:57:48ZrusSergo Ordzhonikidze Russian State University for Geological ProspectingИзвестия высших учебных заведений: Геология и разведка0016-77622618-87082016-02-01018186110Ion-exchange adsorption processes in hydrostratisphereV. G. Popov0R. F. Abdrahmanov1Platov South-Russian State Polytechnic University (Novocherkassk Polytechnic Institute)Institute of Geology of Ufa Science Centre of Russian Academy of SciencesOn the basis of field and experimental lithological and hydrochemical investigations carried out in the Volga-Ural sedimentary basin, a number of important provisions related to the mechanism and kinetics of cation exchange in a heterogeneous system of water-rock have been done. It has been established that they are zonal and differentiated by the depth of the basin. The most significant ion-exchange interaction is in the top of the supergene zone (up to 300 m) with Upper Permian argillaceous sediments with high adsorption properties. Here a radical metamorphic composition of underground fluids and formation of fresh sodium bicarbonate and sodium sulfate salty waters are marked. In areas of catagenesis and metagenesis at the depths greater than 1000-1500 m as a result of the restructuring of the clay minerals in the series of montmorillonite-hydromica-chlorite, the absorption capacity of the adsorption complex of clastic formations of Paleozoic and Late Proterozoic is sharply reduced. Exchange adsorption loses its geochemical significance and plays no significant role in the formation of calcium chloride brines. Their origin is associated with the processes of epigenetic dolomitization of limestone under the influence of density convection of the sodium chloride and magnesium brines from the Permian evaporate paleobasins.https://www.geology-mgri.ru/jour/article/view/110hypergenesiskatagenesisexchange adsorptionsodium bicarbonatesodium sulfatecalcium chloride watergeochemistry
spellingShingle V. G. Popov
R. F. Abdrahmanov
Ion-exchange adsorption processes in hydrostratisphere
Известия высших учебных заведений: Геология и разведка
hypergenesis
katagenesis
exchange adsorption
sodium bicarbonate
sodium sulfate
calcium chloride water
geochemistry
title Ion-exchange adsorption processes in hydrostratisphere
title_full Ion-exchange adsorption processes in hydrostratisphere
title_fullStr Ion-exchange adsorption processes in hydrostratisphere
title_full_unstemmed Ion-exchange adsorption processes in hydrostratisphere
title_short Ion-exchange adsorption processes in hydrostratisphere
title_sort ion exchange adsorption processes in hydrostratisphere
topic hypergenesis
katagenesis
exchange adsorption
sodium bicarbonate
sodium sulfate
calcium chloride water
geochemistry
url https://www.geology-mgri.ru/jour/article/view/110
work_keys_str_mv AT vgpopov ionexchangeadsorptionprocessesinhydrostratisphere
AT rfabdrahmanov ionexchangeadsorptionprocessesinhydrostratisphere