Catalytic Cascade Dehydration-Etherification of Fructose into 5-Ethoxymethylfurfural with SO3H-Functionalized Polymers
A series of SO3H-functionalized polymers were prepared and employed as heterogeneous catalysts for one-pot transformation of fructose into 5-ethoxymethylfurfural (EMF) that is considered to be one of potential liquid biofuels. A high EMF yield of 72.8% could be obtained at 110°C for 10 h, and the po...
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| Format: | Article |
| Language: | English |
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Wiley
2014-01-01
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| Series: | International Journal of Chemical Engineering |
| Online Access: | http://dx.doi.org/10.1155/2014/481627 |
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| _version_ | 1832567771782709248 |
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| author | Hu Li Qiuyun Zhang Song Yang |
| author_facet | Hu Li Qiuyun Zhang Song Yang |
| author_sort | Hu Li |
| collection | DOAJ |
| description | A series of SO3H-functionalized polymers were prepared and employed as heterogeneous catalysts for one-pot transformation of fructose into 5-ethoxymethylfurfural (EMF) that is considered to be one of potential liquid biofuels. A high EMF yield of 72.8% could be obtained at 110°C for 10 h, and the polymeric acid catalysts could be recycled for five times without significant loss of catalytic performance. |
| format | Article |
| id | doaj-art-033f2090f8864909a4926c7873a0b8cb |
| institution | Kabale University |
| issn | 1687-806X 1687-8078 |
| language | English |
| publishDate | 2014-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | International Journal of Chemical Engineering |
| spelling | doaj-art-033f2090f8864909a4926c7873a0b8cb2025-02-03T01:00:34ZengWileyInternational Journal of Chemical Engineering1687-806X1687-80782014-01-01201410.1155/2014/481627481627Catalytic Cascade Dehydration-Etherification of Fructose into 5-Ethoxymethylfurfural with SO3H-Functionalized PolymersHu Li0Qiuyun Zhang1Song Yang2State-Local Joint Laboratory for Comprehensive Utilization of Biomass, State Key Laboratory Breeding Base of Green Pesticide and Agricultural Bioengineering (Ministry of Education), Center for Research and Development of Fine Chemicals, Guizhou University, Guiyang 550025, ChinaState-Local Joint Laboratory for Comprehensive Utilization of Biomass, State Key Laboratory Breeding Base of Green Pesticide and Agricultural Bioengineering (Ministry of Education), Center for Research and Development of Fine Chemicals, Guizhou University, Guiyang 550025, ChinaState-Local Joint Laboratory for Comprehensive Utilization of Biomass, State Key Laboratory Breeding Base of Green Pesticide and Agricultural Bioengineering (Ministry of Education), Center for Research and Development of Fine Chemicals, Guizhou University, Guiyang 550025, ChinaA series of SO3H-functionalized polymers were prepared and employed as heterogeneous catalysts for one-pot transformation of fructose into 5-ethoxymethylfurfural (EMF) that is considered to be one of potential liquid biofuels. A high EMF yield of 72.8% could be obtained at 110°C for 10 h, and the polymeric acid catalysts could be recycled for five times without significant loss of catalytic performance.http://dx.doi.org/10.1155/2014/481627 |
| spellingShingle | Hu Li Qiuyun Zhang Song Yang Catalytic Cascade Dehydration-Etherification of Fructose into 5-Ethoxymethylfurfural with SO3H-Functionalized Polymers International Journal of Chemical Engineering |
| title | Catalytic Cascade Dehydration-Etherification of Fructose into 5-Ethoxymethylfurfural with SO3H-Functionalized Polymers |
| title_full | Catalytic Cascade Dehydration-Etherification of Fructose into 5-Ethoxymethylfurfural with SO3H-Functionalized Polymers |
| title_fullStr | Catalytic Cascade Dehydration-Etherification of Fructose into 5-Ethoxymethylfurfural with SO3H-Functionalized Polymers |
| title_full_unstemmed | Catalytic Cascade Dehydration-Etherification of Fructose into 5-Ethoxymethylfurfural with SO3H-Functionalized Polymers |
| title_short | Catalytic Cascade Dehydration-Etherification of Fructose into 5-Ethoxymethylfurfural with SO3H-Functionalized Polymers |
| title_sort | catalytic cascade dehydration etherification of fructose into 5 ethoxymethylfurfural with so3h functionalized polymers |
| url | http://dx.doi.org/10.1155/2014/481627 |
| work_keys_str_mv | AT huli catalyticcascadedehydrationetherificationoffructoseinto5ethoxymethylfurfuralwithso3hfunctionalizedpolymers AT qiuyunzhang catalyticcascadedehydrationetherificationoffructoseinto5ethoxymethylfurfuralwithso3hfunctionalizedpolymers AT songyang catalyticcascadedehydrationetherificationoffructoseinto5ethoxymethylfurfuralwithso3hfunctionalizedpolymers |