STUDIES OF TRANSITION METAL COMPLEXES WITH 2N-QUINOLYL- AND 2N-ISOQUINOLYL- 1,1,3,3-TETRAMETHY LGUANIDINES
Ligands derived from 8-quinoline, 6-quinoline, 1 -isoquinoline, and 5-isoquinoline were synthesized. These compounds have been used as ligands for complexation of transition metals, such as copper(II) and nickel(II). According to the spectrosocopic data, copper(II) cation forms (I: 1) and (I:2) comp...
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| Format: | Article |
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| Language: | English |
| Published: |
University of Tehran
1996-12-01
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| Series: | Journal of Sciences, Islamic Republic of Iran |
| Online Access: | https://jsciences.ut.ac.ir/article_31133_c09cbdfb559ce5201e2a6d4507a083bd.pdf |
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| Summary: | Ligands derived from 8-quinoline, 6-quinoline, 1 -isoquinoline, and 5-isoquinoline
were synthesized. These compounds have been used as ligands for complexation of
transition metals, such as copper(II) and nickel(II). According to the spectrosocopic
data, copper(II) cation forms (I: 1) and (I:2) complexes with 2-(8-quinoly1)-l,l,3,3- tetramethylguanidine and 2- (I '-isoquinoly1)- 1,1,3,3-tetramethylguanidine, respectively. In contrast, 2-(6'-quinoly1)- 1, l,3,3-tetramethylguanidine and 2-(5'-isoquinoly1)- 1,1,3,3-tetramethylguanidine ligands were shown only in (1: 1) metal-ligand complex. When these ligands are reacted with nickel(II), the same results are obtained. |
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| ISSN: | 1016-1104 2345-6914 |