Et2NH2C6H3(CO2)3SnBr2.4H2O: SYNTHESIS AND INFRARED STUDY
The title compound has been obtained on allowing [C6H3(CO2)3(Et2NH2)3] to react with SnBr4. The molecular structure of Et2NH2C6H3(CO2)3SnBr2.4H2O has been determined on the basis of the infrared data. The suggested structure is a dimer in which each tin atom is hexacoordinated by two chelating C6H3(...
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| Format: | Article |
| Language: | English |
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Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
2014-01-01
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| Series: | Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry |
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| Online Access: | http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201302&vol=2&aid=3919 |
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| author | DAOUDA NDOYE LIBASSE DIOP |
| author_facet | DAOUDA NDOYE LIBASSE DIOP |
| author_sort | DAOUDA NDOYE |
| collection | DOAJ |
| description | The title compound has been obtained on allowing [C6H3(CO2)3(Et2NH2)3] to react with SnBr4. The molecular structure of Et2NH2C6H3(CO2)3SnBr2.4H2O has been determined on the basis of the infrared data. The suggested structure is a dimer in which each tin atom is hexacoordinated by two chelating C6H3(CO2)33- anions and two Br atoms. Cy2NH2+cations are involved through hydrogen bonds with non-coordinating CO2 groups. The suggested structure is a cage. |
| format | Article |
| id | doaj-art-031e7d6282d048c7bff6c5961a264b08 |
| institution | Kabale University |
| issn | 1582-540X |
| language | English |
| publishDate | 2014-01-01 |
| publisher | Alma Mater Publishing House "Vasile Alecsandri" University of Bacau |
| record_format | Article |
| series | Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry |
| spelling | doaj-art-031e7d6282d048c7bff6c5961a264b082025-08-20T03:49:12ZengAlma Mater Publishing House "Vasile Alecsandri" University of BacauScientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry1582-540X2014-01-01142123126Et2NH2C6H3(CO2)3SnBr2.4H2O: SYNTHESIS AND INFRARED STUDYDAOUDA NDOYE0LIBASSE DIOP 1Université Cheikh Anta Diop, Faculté des Sciences et Techniques, Département de Chimie, Laboratoire de Chimie Minérale et Analytique (LACHIMIA), Dakar, SénégalUniversité Cheikh Anta Diop, Faculté des Sciences et Techniques, Département de Chimie, Laboratoire de Chimie Minérale et Analytique (LACHIMIA), Dakar, SénégalThe title compound has been obtained on allowing [C6H3(CO2)3(Et2NH2)3] to react with SnBr4. The molecular structure of Et2NH2C6H3(CO2)3SnBr2.4H2O has been determined on the basis of the infrared data. The suggested structure is a dimer in which each tin atom is hexacoordinated by two chelating C6H3(CO2)33- anions and two Br atoms. Cy2NH2+cations are involved through hydrogen bonds with non-coordinating CO2 groups. The suggested structure is a cage.http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201302&vol=2&aid=3919cagechelatingdimerhexacoordinatedoctahedral environment |
| spellingShingle | DAOUDA NDOYE LIBASSE DIOP Et2NH2C6H3(CO2)3SnBr2.4H2O: SYNTHESIS AND INFRARED STUDY Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry cage chelating dimer hexacoordinated octahedral environment |
| title | Et2NH2C6H3(CO2)3SnBr2.4H2O: SYNTHESIS AND INFRARED STUDY |
| title_full | Et2NH2C6H3(CO2)3SnBr2.4H2O: SYNTHESIS AND INFRARED STUDY |
| title_fullStr | Et2NH2C6H3(CO2)3SnBr2.4H2O: SYNTHESIS AND INFRARED STUDY |
| title_full_unstemmed | Et2NH2C6H3(CO2)3SnBr2.4H2O: SYNTHESIS AND INFRARED STUDY |
| title_short | Et2NH2C6H3(CO2)3SnBr2.4H2O: SYNTHESIS AND INFRARED STUDY |
| title_sort | et2nh2c6h3 co2 3snbr2 4h2o synthesis and infrared study |
| topic | cage chelating dimer hexacoordinated octahedral environment |
| url | http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201302&vol=2&aid=3919 |
| work_keys_str_mv | AT daoudandoye et2nh2c6h3co23snbr24h2osynthesisandinfraredstudy AT libassediop et2nh2c6h3co23snbr24h2osynthesisandinfraredstudy |