Synthesis and characterization of functional copolymer/organo-silicate nanoarchitectures through interlamellar complex-radical (co)terpolymerization
The functional copolymers, having a combination of rigid/flexible linkages and an ability of complex-formation with interlayered surface of organo-silicate, and their nanocomposites have been synthesized by interlamellar complex-radical (co)terpolymerization of intercalated monomer complexes of male...
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| Language: | English |
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Budapest University of Technology and Economics
2008-09-01
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| Series: | eXPRESS Polymer Letters |
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| Online Access: | http://www.expresspolymlett.com/letolt.php?file=EPL-0000714&mi=cd |
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| description | The functional copolymers, having a combination of rigid/flexible linkages and an ability of complex-formation with interlayered surface of organo-silicate, and their nanocomposites have been synthesized by interlamellar complex-radical (co)terpolymerization of intercalated monomer complexes of maleic anhydride (MA) and itaconic acid (IA) with dimethyl dodecylamine surface modified montmorillonite (organo-MMT) (MA…DMDA-MMT and IA…DMDA-MMT) n-butyl methacrylate (BMA) and/or BMA/styrene monomer mixtures. The results of nanocomposite structure–composition– property relationship studies indicate that interlamellar complex-formation between anhydride/acid units and surface alkyl amine and rigid/flexible linkage balance in polymer chains are important factors providing the effective intercalation/ exfoliation of the polymer chains into the silicate galleries, the formation of nanostructural hybrids with higher thermal stability, dynamic mechanical behaviour and well dispersed morphology. |
| format | Article |
| id | doaj-art-028cf8de78fd4123ad83f9fd6a4c154d |
| institution | Kabale University |
| issn | 1788-618X |
| language | English |
| publishDate | 2008-09-01 |
| publisher | Budapest University of Technology and Economics |
| record_format | Article |
| series | eXPRESS Polymer Letters |
| spelling | doaj-art-028cf8de78fd4123ad83f9fd6a4c154d2025-08-20T03:32:47ZengBudapest University of Technology and EconomicseXPRESS Polymer Letters1788-618X2008-09-012963965410.3144/expresspolymlett.2008.77Synthesis and characterization of functional copolymer/organo-silicate nanoarchitectures through interlamellar complex-radical (co)terpolymerizationThe functional copolymers, having a combination of rigid/flexible linkages and an ability of complex-formation with interlayered surface of organo-silicate, and their nanocomposites have been synthesized by interlamellar complex-radical (co)terpolymerization of intercalated monomer complexes of maleic anhydride (MA) and itaconic acid (IA) with dimethyl dodecylamine surface modified montmorillonite (organo-MMT) (MA…DMDA-MMT and IA…DMDA-MMT) n-butyl methacrylate (BMA) and/or BMA/styrene monomer mixtures. The results of nanocomposite structure–composition– property relationship studies indicate that interlamellar complex-formation between anhydride/acid units and surface alkyl amine and rigid/flexible linkage balance in polymer chains are important factors providing the effective intercalation/ exfoliation of the polymer chains into the silicate galleries, the formation of nanostructural hybrids with higher thermal stability, dynamic mechanical behaviour and well dispersed morphology.http://www.expresspolymlett.com/letolt.php?file=EPL-0000714&mi=cdPolymer synthesis, molecular einterlamellar copolymerizationnanocompositesdynamic mechanical propertiesmorphology |
| spellingShingle | Synthesis and characterization of functional copolymer/organo-silicate nanoarchitectures through interlamellar complex-radical (co)terpolymerization eXPRESS Polymer Letters Polymer synthesis, molecular e interlamellar copolymerization nanocomposites dynamic mechanical properties morphology |
| title | Synthesis and characterization of functional copolymer/organo-silicate nanoarchitectures through interlamellar complex-radical (co)terpolymerization |
| title_full | Synthesis and characterization of functional copolymer/organo-silicate nanoarchitectures through interlamellar complex-radical (co)terpolymerization |
| title_fullStr | Synthesis and characterization of functional copolymer/organo-silicate nanoarchitectures through interlamellar complex-radical (co)terpolymerization |
| title_full_unstemmed | Synthesis and characterization of functional copolymer/organo-silicate nanoarchitectures through interlamellar complex-radical (co)terpolymerization |
| title_short | Synthesis and characterization of functional copolymer/organo-silicate nanoarchitectures through interlamellar complex-radical (co)terpolymerization |
| title_sort | synthesis and characterization of functional copolymer organo silicate nanoarchitectures through interlamellar complex radical co terpolymerization |
| topic | Polymer synthesis, molecular e interlamellar copolymerization nanocomposites dynamic mechanical properties morphology |
| url | http://www.expresspolymlett.com/letolt.php?file=EPL-0000714&mi=cd |