Sorption of Triclosan onto Tyre Crumb Rubber

The effectiveness of using tyre crumb rubber (TCR) as an adsorbent for the removal of triclosan (TCS) from aqueous solutions was evaluated as a function of pH through controlled batch experiments. Carbon black (CB) and styrene–butadiene polymer (SBP), which are the main components in TCR, were indiv...

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Main Authors: J. López-Morales, O. Perales-Pérez, F. Román-Velázquez
Format: Article
Language:English
Published: SAGE Publishing 2012-12-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1260/0263-6174.30.10.831
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author J. López-Morales
O. Perales-Pérez
F. Román-Velázquez
author_facet J. López-Morales
O. Perales-Pérez
F. Román-Velázquez
author_sort J. López-Morales
collection DOAJ
description The effectiveness of using tyre crumb rubber (TCR) as an adsorbent for the removal of triclosan (TCS) from aqueous solutions was evaluated as a function of pH through controlled batch experiments. Carbon black (CB) and styrene–butadiene polymer (SBP), which are the main components in TCR, were individually evaluated and their contribution in the sorption process was assessed. At pH 3, the maximum rate of adsorption of TCS onto TCR, CB and SBP was 89, 95 and 92%, respectively. The Freundlich model provided the best fit for the experimental data obtained, as indicated by the mean relative percent deviation modulus (P). Our study results indicate that the removal of TCS using SBP follows an absorption process. Maximum desorption rate of TCS from TCR was approximately 89%. Results of sorption/desorption experiments clearly indicated the viability of TCR to be reused without any significant loss in its sorption/desorption capacity.
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institution Kabale University
issn 0263-6174
2048-4038
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publishDate 2012-12-01
publisher SAGE Publishing
record_format Article
series Adsorption Science & Technology
spelling doaj-art-028a21b8e3c64a2288356226e3ac675d2025-02-03T10:08:00ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40382012-12-013010.1260/0263-6174.30.10.831Sorption of Triclosan onto Tyre Crumb RubberJ. López-Morales0O. Perales-Pérez1F. Román-Velázquez2 Department of Chemistry, University of Puerto Rico, Mayagüez, Puerto Rico, 00680 Department of Engineering Science and Materials, University of Puerto Rico, Mayagüez, Puerto Rico, 00680 Department of Chemistry, University of Puerto Rico, Mayagüez, Puerto Rico, 00680The effectiveness of using tyre crumb rubber (TCR) as an adsorbent for the removal of triclosan (TCS) from aqueous solutions was evaluated as a function of pH through controlled batch experiments. Carbon black (CB) and styrene–butadiene polymer (SBP), which are the main components in TCR, were individually evaluated and their contribution in the sorption process was assessed. At pH 3, the maximum rate of adsorption of TCS onto TCR, CB and SBP was 89, 95 and 92%, respectively. The Freundlich model provided the best fit for the experimental data obtained, as indicated by the mean relative percent deviation modulus (P). Our study results indicate that the removal of TCS using SBP follows an absorption process. Maximum desorption rate of TCS from TCR was approximately 89%. Results of sorption/desorption experiments clearly indicated the viability of TCR to be reused without any significant loss in its sorption/desorption capacity.https://doi.org/10.1260/0263-6174.30.10.831
spellingShingle J. López-Morales
O. Perales-Pérez
F. Román-Velázquez
Sorption of Triclosan onto Tyre Crumb Rubber
Adsorption Science & Technology
title Sorption of Triclosan onto Tyre Crumb Rubber
title_full Sorption of Triclosan onto Tyre Crumb Rubber
title_fullStr Sorption of Triclosan onto Tyre Crumb Rubber
title_full_unstemmed Sorption of Triclosan onto Tyre Crumb Rubber
title_short Sorption of Triclosan onto Tyre Crumb Rubber
title_sort sorption of triclosan onto tyre crumb rubber
url https://doi.org/10.1260/0263-6174.30.10.831
work_keys_str_mv AT jlopezmorales sorptionoftriclosanontotyrecrumbrubber
AT operalesperez sorptionoftriclosanontotyrecrumbrubber
AT fromanvelazquez sorptionoftriclosanontotyrecrumbrubber