Pressure-dependent current transport in vertical BP/MoS2 heterostructures

van der Waals heterostructures between two-dimensional (2D) materials offer versatile platforms for innovative electrical device architectures and applications. Black phosphorus (BP) and molybdenum disulfide (MoS2) emerge as promising candidates for heterostructures, owing to their exceptional elect...

Full description

Saved in:
Bibliographic Details
Main Authors: Ofelia Durante, Sebastiano De Stefano, Adolfo Mazzotti, Loredana Viscardi, Filippo Giubileo, Osamah Kharsah, Leon Daniel, Stephan Sleziona, Marika Schleberger, Antonio Di Bartolomeo
Format: Article
Language:English
Published: Elsevier 2025-02-01
Series:Heliyon
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2405844025008230
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1825206841145032704
author Ofelia Durante
Sebastiano De Stefano
Adolfo Mazzotti
Loredana Viscardi
Filippo Giubileo
Osamah Kharsah
Leon Daniel
Stephan Sleziona
Marika Schleberger
Antonio Di Bartolomeo
author_facet Ofelia Durante
Sebastiano De Stefano
Adolfo Mazzotti
Loredana Viscardi
Filippo Giubileo
Osamah Kharsah
Leon Daniel
Stephan Sleziona
Marika Schleberger
Antonio Di Bartolomeo
author_sort Ofelia Durante
collection DOAJ
description van der Waals heterostructures between two-dimensional (2D) materials offer versatile platforms for innovative electrical device architectures and applications. Black phosphorus (BP) and molybdenum disulfide (MoS2) emerge as promising candidates for heterostructures, owing to their exceptional electronic properties and gate-tunable capabilities. In this work, we study the electrical properties of a vertical BP/MoS2 heterostructure fabricated onto a SiO2/Si substrate in a back-gate configuration. We focus on the effect of air pressure, from atmospheric pressure to 10−4 mbar, and show that best electrical performances are enabled at the lower pressure. The heterostructure exhibits gate-tunable rectifying current-voltage characteristics, with a rectification ratio close to 103. The rectifying characteristics present a kink in the forward region revealing different conduction mechanisms, namely drift-diffusion and band-to-band tunneling. Furthermore, when used as a transistor, the device shows n-type conduction, high gate modulation with ON/OFF ratio of 106, low off-state current of 10−14A and mobility of 1.6 cm2 V−1 s−1. The results of this work highlight the potential of BP/MoS2 heterostructures for applications in low-power electronics, high-performance transistors, and sensitive pressure sensors.
format Article
id doaj-art-0226d2c4e83b498ebc65eb6073d08a10
institution Kabale University
issn 2405-8440
language English
publishDate 2025-02-01
publisher Elsevier
record_format Article
series Heliyon
spelling doaj-art-0226d2c4e83b498ebc65eb6073d08a102025-02-07T04:47:57ZengElsevierHeliyon2405-84402025-02-01113e42443Pressure-dependent current transport in vertical BP/MoS2 heterostructuresOfelia Durante0Sebastiano De Stefano1Adolfo Mazzotti2Loredana Viscardi3Filippo Giubileo4Osamah Kharsah5Leon Daniel6Stephan Sleziona7Marika Schleberger8Antonio Di Bartolomeo9Department of Physics “E. R. Caianiello”, University of Salerno, via Giovanni Paolo II, Fisciano, Salerno, 84084, ItalyDepartment of Physics “E. R. Caianiello”, University of Salerno, via Giovanni Paolo II, Fisciano, Salerno, 84084, ItalyDepartment of Physics “E. R. Caianiello”, University of Salerno, via Giovanni Paolo II, Fisciano, Salerno, 84084, ItalyDepartment of Physics “E. R. Caianiello”, University of Salerno, via Giovanni Paolo II, Fisciano, Salerno, 84084, ItalyCNR-SPIN, via Giovanni Paolo II, Fisciano, Salerno, 84084, ItalyFakultät für Physik and CENIDE, Universität Duisburg-Essen, Lotharstrasse 1, Duisburg D-47057, GermanyFakultät für Physik and CENIDE, Universität Duisburg-Essen, Lotharstrasse 1, Duisburg D-47057, GermanyFakultät für Physik and CENIDE, Universität Duisburg-Essen, Lotharstrasse 1, Duisburg D-47057, GermanyFakultät für Physik and CENIDE, Universität Duisburg-Essen, Lotharstrasse 1, Duisburg D-47057, Germany; Corresponding author.Department of Physics “E. R. Caianiello”, University of Salerno, via Giovanni Paolo II, Fisciano, Salerno, 84084, Italy; Corresponding author.van der Waals heterostructures between two-dimensional (2D) materials offer versatile platforms for innovative electrical device architectures and applications. Black phosphorus (BP) and molybdenum disulfide (MoS2) emerge as promising candidates for heterostructures, owing to their exceptional electronic properties and gate-tunable capabilities. In this work, we study the electrical properties of a vertical BP/MoS2 heterostructure fabricated onto a SiO2/Si substrate in a back-gate configuration. We focus on the effect of air pressure, from atmospheric pressure to 10−4 mbar, and show that best electrical performances are enabled at the lower pressure. The heterostructure exhibits gate-tunable rectifying current-voltage characteristics, with a rectification ratio close to 103. The rectifying characteristics present a kink in the forward region revealing different conduction mechanisms, namely drift-diffusion and band-to-band tunneling. Furthermore, when used as a transistor, the device shows n-type conduction, high gate modulation with ON/OFF ratio of 106, low off-state current of 10−14A and mobility of 1.6 cm2 V−1 s−1. The results of this work highlight the potential of BP/MoS2 heterostructures for applications in low-power electronics, high-performance transistors, and sensitive pressure sensors.http://www.sciencedirect.com/science/article/pii/S2405844025008230PressureKinkThermionicTunnelingRectification ratioBP
spellingShingle Ofelia Durante
Sebastiano De Stefano
Adolfo Mazzotti
Loredana Viscardi
Filippo Giubileo
Osamah Kharsah
Leon Daniel
Stephan Sleziona
Marika Schleberger
Antonio Di Bartolomeo
Pressure-dependent current transport in vertical BP/MoS2 heterostructures
Heliyon
Pressure
Kink
Thermionic
Tunneling
Rectification ratio
BP
title Pressure-dependent current transport in vertical BP/MoS2 heterostructures
title_full Pressure-dependent current transport in vertical BP/MoS2 heterostructures
title_fullStr Pressure-dependent current transport in vertical BP/MoS2 heterostructures
title_full_unstemmed Pressure-dependent current transport in vertical BP/MoS2 heterostructures
title_short Pressure-dependent current transport in vertical BP/MoS2 heterostructures
title_sort pressure dependent current transport in vertical bp mos2 heterostructures
topic Pressure
Kink
Thermionic
Tunneling
Rectification ratio
BP
url http://www.sciencedirect.com/science/article/pii/S2405844025008230
work_keys_str_mv AT ofeliadurante pressuredependentcurrenttransportinverticalbpmos2heterostructures
AT sebastianodestefano pressuredependentcurrenttransportinverticalbpmos2heterostructures
AT adolfomazzotti pressuredependentcurrenttransportinverticalbpmos2heterostructures
AT loredanaviscardi pressuredependentcurrenttransportinverticalbpmos2heterostructures
AT filippogiubileo pressuredependentcurrenttransportinverticalbpmos2heterostructures
AT osamahkharsah pressuredependentcurrenttransportinverticalbpmos2heterostructures
AT leondaniel pressuredependentcurrenttransportinverticalbpmos2heterostructures
AT stephansleziona pressuredependentcurrenttransportinverticalbpmos2heterostructures
AT marikaschleberger pressuredependentcurrenttransportinverticalbpmos2heterostructures
AT antoniodibartolomeo pressuredependentcurrenttransportinverticalbpmos2heterostructures