Distribution and isotopic compositions of n-alkanes and n-alkenes in the cryoconites from the Tibetan Plateau glaciers

In the current study, cryoconite samples were collected from six glaciers on the Tibetan Plateau to analyze n-alkanes and n-alkenes. The findings revealed that the concentrations of n-alkanes and n-alkenes varied from 40.1 to 496.1 μg g−1 and from 4.6 to 13.8 μg g−1, respectively. The carbon prefere...

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Main Authors: Quanlian Li, Shichang Kang, Shijin Wang, Ninglian Wang, Xiaobo Wu, Wasim Sajjad, Huan Yang, Yao Li, Jingquan Wu
Format: Article
Language:English
Published: Cambridge University Press 2024-01-01
Series:Journal of Glaciology
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Online Access:https://www.cambridge.org/core/product/identifier/S0022143024000236/type/journal_article
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_version_ 1841526395178582016
author Quanlian Li
Shichang Kang
Shijin Wang
Ninglian Wang
Xiaobo Wu
Wasim Sajjad
Huan Yang
Yao Li
Jingquan Wu
author_facet Quanlian Li
Shichang Kang
Shijin Wang
Ninglian Wang
Xiaobo Wu
Wasim Sajjad
Huan Yang
Yao Li
Jingquan Wu
author_sort Quanlian Li
collection DOAJ
description In the current study, cryoconite samples were collected from six glaciers on the Tibetan Plateau to analyze n-alkanes and n-alkenes. The findings revealed that the concentrations of n-alkanes and n-alkenes varied from 40.1 to 496.1 μg g−1 and from 4.6 to 13.8 μg g−1, respectively. The carbon preference index of the long-chain n-alkanes ranged from 3.3 to 8.4, and the average chain length ranged from 28.7 to 29.3. Moreover, the δ13C of the n-alkanes in cryoconites were within the range of C3 plants, demonstrating that the n-alkanes in cryoconites were only derived from vascular plants. However, the δDmean were more negative than that of C3 plants, which could be caused by dry and humid conditions of glaciers. Unlike n-alkanes, n-alkenes ranged from C17:1 to C30:1 and showed a weak even-over-odd carbon number preference in the Dongkemadi, Yuzhufeng, Laohugou and Tianshan glacier, but a weak odd carbon preference in the Qiyi glacier. The n-alkenes in the YL Snow Mountains showed an obvious odd-over-even carbon number predominance from C17:1 to C22:1 with Cmax at C19:1, and the even-over-odd carbon number preference from C23:1 to C30:1 with Cmax at C28:1. This demonstrated that the n-alkenes of cryoconites may be mainly derived from in situ production in glaciers.
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spelling doaj-art-01d44a6862824882b60c22ac61a05f9b2025-01-16T21:52:40ZengCambridge University PressJournal of Glaciology0022-14301727-56522024-01-017010.1017/jog.2024.23Distribution and isotopic compositions of n-alkanes and n-alkenes in the cryoconites from the Tibetan Plateau glaciersQuanlian Li0https://orcid.org/0000-0002-4684-1062Shichang Kang1Shijin Wang2Ninglian Wang3Xiaobo Wu4Wasim Sajjad5Huan Yang6Yao Li7Jingquan Wu8Northwest Institute of Eco-Environment and Resources, State Key Laboratory of Frozen Soil Engineering, SKLCS Lanzhou, Gansu, CN, CAS, Lanzhou 730000, China Yulong Snow Mountain Station of Cryosphere and Sustainable Development, State Key Laboratory of Cryospheric Sciences, Northwest Institute of Eco-Environment and Resources, Chinese Academy of Sciences, Lanzhou 730000, ChinaNorthwest Institute of Eco-Environment and Resources, State Key Laboratory of Frozen Soil Engineering, SKLCS Lanzhou, Gansu, CN, CAS, Lanzhou 730000, China University of Chinese Academy of Sciences, Beijing 100049, ChinaNorthwest Institute of Eco-Environment and Resources, State Key Laboratory of Frozen Soil Engineering, SKLCS Lanzhou, Gansu, CN, CAS, Lanzhou 730000, China Yulong Snow Mountain Station of Cryosphere and Sustainable Development, State Key Laboratory of Cryospheric Sciences, Northwest Institute of Eco-Environment and Resources, Chinese Academy of Sciences, Lanzhou 730000, ChinaShaanxi Key Laboratory of Earth Surface System and Environmental Carrying Capacity, Xi'an 710127, China Institute of Earth Surface System and Hazards, Northwest University, Xi'an 710127, China College of Urban and Environmental Sciences, Northwest University, Xi'an 710127, ChinaNorthwest Institute of Eco-Environment and Resources, State Key Laboratory of Frozen Soil Engineering, SKLCS Lanzhou, Gansu, CN, CAS, Lanzhou 730000, ChinaNorthwest Institute of Eco-Environment and Resources, State Key Laboratory of Frozen Soil Engineering, SKLCS Lanzhou, Gansu, CN, CAS, Lanzhou 730000, ChinaHubei Key Laboratory of Critical Zone Evolution, School of Geography and Information Engineering, China University of Geosciences, Wuhan 430074, ChinaNorthwest Institute of Eco-Environment and Resources, State Key Laboratory of Frozen Soil Engineering, SKLCS Lanzhou, Gansu, CN, CAS, Lanzhou 730000, ChinaNorthwest Institute of Eco-Environment and Resources, State Key Laboratory of Frozen Soil Engineering, SKLCS Lanzhou, Gansu, CN, CAS, Lanzhou 730000, ChinaIn the current study, cryoconite samples were collected from six glaciers on the Tibetan Plateau to analyze n-alkanes and n-alkenes. The findings revealed that the concentrations of n-alkanes and n-alkenes varied from 40.1 to 496.1 μg g−1 and from 4.6 to 13.8 μg g−1, respectively. The carbon preference index of the long-chain n-alkanes ranged from 3.3 to 8.4, and the average chain length ranged from 28.7 to 29.3. Moreover, the δ13C of the n-alkanes in cryoconites were within the range of C3 plants, demonstrating that the n-alkanes in cryoconites were only derived from vascular plants. However, the δDmean were more negative than that of C3 plants, which could be caused by dry and humid conditions of glaciers. Unlike n-alkanes, n-alkenes ranged from C17:1 to C30:1 and showed a weak even-over-odd carbon number preference in the Dongkemadi, Yuzhufeng, Laohugou and Tianshan glacier, but a weak odd carbon preference in the Qiyi glacier. The n-alkenes in the YL Snow Mountains showed an obvious odd-over-even carbon number predominance from C17:1 to C22:1 with Cmax at C19:1, and the even-over-odd carbon number preference from C23:1 to C30:1 with Cmax at C28:1. This demonstrated that the n-alkenes of cryoconites may be mainly derived from in situ production in glaciers.https://www.cambridge.org/core/product/identifier/S0022143024000236/type/journal_articlecryoconiteglaciern-alkanen-alkeneTibetan Plateau
spellingShingle Quanlian Li
Shichang Kang
Shijin Wang
Ninglian Wang
Xiaobo Wu
Wasim Sajjad
Huan Yang
Yao Li
Jingquan Wu
Distribution and isotopic compositions of n-alkanes and n-alkenes in the cryoconites from the Tibetan Plateau glaciers
Journal of Glaciology
cryoconite
glacier
n-alkane
n-alkene
Tibetan Plateau
title Distribution and isotopic compositions of n-alkanes and n-alkenes in the cryoconites from the Tibetan Plateau glaciers
title_full Distribution and isotopic compositions of n-alkanes and n-alkenes in the cryoconites from the Tibetan Plateau glaciers
title_fullStr Distribution and isotopic compositions of n-alkanes and n-alkenes in the cryoconites from the Tibetan Plateau glaciers
title_full_unstemmed Distribution and isotopic compositions of n-alkanes and n-alkenes in the cryoconites from the Tibetan Plateau glaciers
title_short Distribution and isotopic compositions of n-alkanes and n-alkenes in the cryoconites from the Tibetan Plateau glaciers
title_sort distribution and isotopic compositions of n alkanes and n alkenes in the cryoconites from the tibetan plateau glaciers
topic cryoconite
glacier
n-alkane
n-alkene
Tibetan Plateau
url https://www.cambridge.org/core/product/identifier/S0022143024000236/type/journal_article
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