Synthesis, Spectroscopic, and Characterization of Novel Nano Sized Mannich Base Complexes with Pt (IV) and Au (III) Ions and Assessing Their Antioxidants Activity

This study focuses on the synthesis of nano pt(IV) and Au(III) Mannich base complexes derived from ciprofloxacin by the ultrasonic sonication method. The size and morphology of nanocomplex were measured by transmission electron microscopy (TEM), atomic force microscopy (AFM), energy dispersive X-ra...

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Main Authors: Alya'a J. Ahmed, Mahasin F. Alias
Format: Article
Language:English
Published: University of Baghdad, College of Science for Women 2024-10-01
Series:مجلة بغداد للعلوم
Subjects:
Online Access:https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/8552
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author Alya'a J. Ahmed
Mahasin F. Alias
author_facet Alya'a J. Ahmed
Mahasin F. Alias
author_sort Alya'a J. Ahmed
collection DOAJ
description This study focuses on the synthesis of nano pt(IV) and Au(III) Mannich base complexes derived from ciprofloxacin by the ultrasonic sonication method. The size and morphology of nanocomplex were measured by transmission electron microscopy (TEM), atomic force microscopy (AFM), energy dispersive X-ray (EDX), scanning electron microscopy (SEM), x-ray differentiation (XRD) and Fourier transform infrared spectroscopy (FTIR). Newly synthesized ligand and their metal complexes were tested for their ability to scavenge free radicals at concentrations between 6.25 and 100 µg/ml using their interaction with the stable free radical 1,1-diphenyl-2-picrylhydrazyl (DPPH). It has been demonstrated that all compounds enhance antioxidant activity in high concentration.
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issn 2078-8665
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language English
publishDate 2024-10-01
publisher University of Baghdad, College of Science for Women
record_format Article
series مجلة بغداد للعلوم
spelling doaj-art-0140b02b4d394c73bc33f9b47e69a0912025-08-20T03:16:22ZengUniversity of Baghdad, College of Science for Womenمجلة بغداد للعلوم2078-86652411-79862024-10-01211010.21123/bsj.2024.8552Synthesis, Spectroscopic, and Characterization of Novel Nano Sized Mannich Base Complexes with Pt (IV) and Au (III) Ions and Assessing Their Antioxidants ActivityAlya'a J. Ahmed0https://orcid.org/0000-0002-1093-2907Mahasin F. Alias 1Ministry of Higher Education and Scientific Research, Baghdad, Iraq Department of Chemistry, College of Science for Women, University of Baghdad, Baghdad, Iraq. This study focuses on the synthesis of nano pt(IV) and Au(III) Mannich base complexes derived from ciprofloxacin by the ultrasonic sonication method. The size and morphology of nanocomplex were measured by transmission electron microscopy (TEM), atomic force microscopy (AFM), energy dispersive X-ray (EDX), scanning electron microscopy (SEM), x-ray differentiation (XRD) and Fourier transform infrared spectroscopy (FTIR). Newly synthesized ligand and their metal complexes were tested for their ability to scavenge free radicals at concentrations between 6.25 and 100 µg/ml using their interaction with the stable free radical 1,1-diphenyl-2-picrylhydrazyl (DPPH). It has been demonstrated that all compounds enhance antioxidant activity in high concentration. https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/8552Antioxidant, Ciprofloxacin, Free radicals, Mannich base complexes, Nano size
spellingShingle Alya'a J. Ahmed
Mahasin F. Alias
Synthesis, Spectroscopic, and Characterization of Novel Nano Sized Mannich Base Complexes with Pt (IV) and Au (III) Ions and Assessing Their Antioxidants Activity
مجلة بغداد للعلوم
Antioxidant, Ciprofloxacin, Free radicals, Mannich base complexes, Nano size
title Synthesis, Spectroscopic, and Characterization of Novel Nano Sized Mannich Base Complexes with Pt (IV) and Au (III) Ions and Assessing Their Antioxidants Activity
title_full Synthesis, Spectroscopic, and Characterization of Novel Nano Sized Mannich Base Complexes with Pt (IV) and Au (III) Ions and Assessing Their Antioxidants Activity
title_fullStr Synthesis, Spectroscopic, and Characterization of Novel Nano Sized Mannich Base Complexes with Pt (IV) and Au (III) Ions and Assessing Their Antioxidants Activity
title_full_unstemmed Synthesis, Spectroscopic, and Characterization of Novel Nano Sized Mannich Base Complexes with Pt (IV) and Au (III) Ions and Assessing Their Antioxidants Activity
title_short Synthesis, Spectroscopic, and Characterization of Novel Nano Sized Mannich Base Complexes with Pt (IV) and Au (III) Ions and Assessing Their Antioxidants Activity
title_sort synthesis spectroscopic and characterization of novel nano sized mannich base complexes with pt iv and au iii ions and assessing their antioxidants activity
topic Antioxidant, Ciprofloxacin, Free radicals, Mannich base complexes, Nano size
url https://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/8552
work_keys_str_mv AT alyaajahmed synthesisspectroscopicandcharacterizationofnovelnanosizedmannichbasecomplexeswithptivandauiiiionsandassessingtheirantioxidantsactivity
AT mahasinfalias synthesisspectroscopicandcharacterizationofnovelnanosizedmannichbasecomplexeswithptivandauiiiionsandassessingtheirantioxidantsactivity