Hydrothermal Synthesis, Structural Characterization, and Interaction Mechanism with DNA of Copper(II) Complex Containing 2,2′-Bipyridine
A Cu(II) complex [Cu(bipy)(H2O)2(SO4)]n (bipy = 2,2′-bipyridine) was synthesized by hydrothermal method and characterized structurally by elemental analyses, single crystal X-ray diffraction, infrared spectra, and thermogravimetry and differential scanning calorimetry. The Cu(II) was hexacoordinated...
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| Format: | Article |
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Wiley
2018-01-01
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| Series: | Bioinorganic Chemistry and Applications |
| Online Access: | http://dx.doi.org/10.1155/2018/8459638 |
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| author | Ting Liu Yi-An Wang Qing Zang Guo-Qing Zhong |
| author_facet | Ting Liu Yi-An Wang Qing Zang Guo-Qing Zhong |
| author_sort | Ting Liu |
| collection | DOAJ |
| description | A Cu(II) complex [Cu(bipy)(H2O)2(SO4)]n (bipy = 2,2′-bipyridine) was synthesized by hydrothermal method and characterized structurally by elemental analyses, single crystal X-ray diffraction, infrared spectra, and thermogravimetry and differential scanning calorimetry. The Cu(II) was hexacoordinated by two N atoms from bipy, two O atoms from different sulfate radical anions, and two O atoms from two water molecules, forming a slightly distorted octahedral geometry, and bridged by sulfato groups into polymeric chains. Under the condition of physiological pH, the interaction mechanism between the complex and hsDNA was explored with acridine orange as a fluorescence probe by spectroscopic methods. The binding modes between the complex and hsDNA were the electrostatic and embedded modes. |
| format | Article |
| id | doaj-art-012014cc35504aebbd22fbb1f4e9df62 |
| institution | DOAJ |
| issn | 1565-3633 1687-479X |
| language | English |
| publishDate | 2018-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Bioinorganic Chemistry and Applications |
| spelling | doaj-art-012014cc35504aebbd22fbb1f4e9df622025-08-20T03:22:33ZengWileyBioinorganic Chemistry and Applications1565-36331687-479X2018-01-01201810.1155/2018/84596388459638Hydrothermal Synthesis, Structural Characterization, and Interaction Mechanism with DNA of Copper(II) Complex Containing 2,2′-BipyridineTing Liu0Yi-An Wang1Qing Zang2Guo-Qing Zhong3School of Material Science and Engineering, Southwest University of Science and Technology, Mianyang 621010, ChinaSchool of Material Science and Engineering, Southwest University of Science and Technology, Mianyang 621010, ChinaSchool of Material Science and Engineering, Southwest University of Science and Technology, Mianyang 621010, ChinaSchool of Material Science and Engineering, Southwest University of Science and Technology, Mianyang 621010, ChinaA Cu(II) complex [Cu(bipy)(H2O)2(SO4)]n (bipy = 2,2′-bipyridine) was synthesized by hydrothermal method and characterized structurally by elemental analyses, single crystal X-ray diffraction, infrared spectra, and thermogravimetry and differential scanning calorimetry. The Cu(II) was hexacoordinated by two N atoms from bipy, two O atoms from different sulfate radical anions, and two O atoms from two water molecules, forming a slightly distorted octahedral geometry, and bridged by sulfato groups into polymeric chains. Under the condition of physiological pH, the interaction mechanism between the complex and hsDNA was explored with acridine orange as a fluorescence probe by spectroscopic methods. The binding modes between the complex and hsDNA were the electrostatic and embedded modes.http://dx.doi.org/10.1155/2018/8459638 |
| spellingShingle | Ting Liu Yi-An Wang Qing Zang Guo-Qing Zhong Hydrothermal Synthesis, Structural Characterization, and Interaction Mechanism with DNA of Copper(II) Complex Containing 2,2′-Bipyridine Bioinorganic Chemistry and Applications |
| title | Hydrothermal Synthesis, Structural Characterization, and Interaction Mechanism with DNA of Copper(II) Complex Containing 2,2′-Bipyridine |
| title_full | Hydrothermal Synthesis, Structural Characterization, and Interaction Mechanism with DNA of Copper(II) Complex Containing 2,2′-Bipyridine |
| title_fullStr | Hydrothermal Synthesis, Structural Characterization, and Interaction Mechanism with DNA of Copper(II) Complex Containing 2,2′-Bipyridine |
| title_full_unstemmed | Hydrothermal Synthesis, Structural Characterization, and Interaction Mechanism with DNA of Copper(II) Complex Containing 2,2′-Bipyridine |
| title_short | Hydrothermal Synthesis, Structural Characterization, and Interaction Mechanism with DNA of Copper(II) Complex Containing 2,2′-Bipyridine |
| title_sort | hydrothermal synthesis structural characterization and interaction mechanism with dna of copper ii complex containing 2 2 bipyridine |
| url | http://dx.doi.org/10.1155/2018/8459638 |
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