Two New 1,1,3,3-Tetramethylguanidinium Halochromates (C5H14N3CrO3X) (X: Cl, F): Efficient Reagents for Oxidation of Organic Substrates under Solvent-Free Conditions and Microwave Irradiation
Two new mild oxidizing agents 1,1,3,3-tetramethylguanidinium fluorochromate (TMGFC) and 1,1,3,3-tetramethylguanidinium chlorochromate (TMGCC) were prepared in high yields by reacting tetramethylguanidine with CrO3 and related acid. These reagents are suitable to oxidize various primary and secondary...
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| Format: | Article |
| Language: | English |
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Wiley
2016-01-01
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| Series: | Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2016/3518102 |
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| author | Kıvılcım Şendıl H. Beytiye Özgün Ebru Üstün |
| author_facet | Kıvılcım Şendıl H. Beytiye Özgün Ebru Üstün |
| author_sort | Kıvılcım Şendıl |
| collection | DOAJ |
| description | Two new mild oxidizing agents 1,1,3,3-tetramethylguanidinium fluorochromate (TMGFC) and 1,1,3,3-tetramethylguanidinium chlorochromate (TMGCC) were prepared in high yields by reacting tetramethylguanidine with CrO3 and related acid. These reagents are suitable to oxidize various primary and secondary alcohols and oximes to the corresponding carbonyl compounds under solvent-free conditions and microwave irradiation. |
| format | Article |
| id | doaj-art-00d90df5546e40bd990179208f9f1230 |
| institution | Kabale University |
| issn | 2090-9063 2090-9071 |
| language | English |
| publishDate | 2016-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Journal of Chemistry |
| spelling | doaj-art-00d90df5546e40bd990179208f9f12302025-02-03T01:02:57ZengWileyJournal of Chemistry2090-90632090-90712016-01-01201610.1155/2016/35181023518102Two New 1,1,3,3-Tetramethylguanidinium Halochromates (C5H14N3CrO3X) (X: Cl, F): Efficient Reagents for Oxidation of Organic Substrates under Solvent-Free Conditions and Microwave IrradiationKıvılcım Şendıl0H. Beytiye Özgün1Ebru Üstün2Department of Chemistry, Faculty of Science, Kafkas University, 36100 Kars, TurkeyDepartment of Chemistry, Faculty of Science, Gazi University, 06100 Ankara, TurkeyDepartment of Chemistry, Faculty of Science, Gazi University, 06100 Ankara, TurkeyTwo new mild oxidizing agents 1,1,3,3-tetramethylguanidinium fluorochromate (TMGFC) and 1,1,3,3-tetramethylguanidinium chlorochromate (TMGCC) were prepared in high yields by reacting tetramethylguanidine with CrO3 and related acid. These reagents are suitable to oxidize various primary and secondary alcohols and oximes to the corresponding carbonyl compounds under solvent-free conditions and microwave irradiation.http://dx.doi.org/10.1155/2016/3518102 |
| spellingShingle | Kıvılcım Şendıl H. Beytiye Özgün Ebru Üstün Two New 1,1,3,3-Tetramethylguanidinium Halochromates (C5H14N3CrO3X) (X: Cl, F): Efficient Reagents for Oxidation of Organic Substrates under Solvent-Free Conditions and Microwave Irradiation Journal of Chemistry |
| title | Two New 1,1,3,3-Tetramethylguanidinium Halochromates (C5H14N3CrO3X) (X: Cl, F): Efficient Reagents for Oxidation of Organic Substrates under Solvent-Free Conditions and Microwave Irradiation |
| title_full | Two New 1,1,3,3-Tetramethylguanidinium Halochromates (C5H14N3CrO3X) (X: Cl, F): Efficient Reagents for Oxidation of Organic Substrates under Solvent-Free Conditions and Microwave Irradiation |
| title_fullStr | Two New 1,1,3,3-Tetramethylguanidinium Halochromates (C5H14N3CrO3X) (X: Cl, F): Efficient Reagents for Oxidation of Organic Substrates under Solvent-Free Conditions and Microwave Irradiation |
| title_full_unstemmed | Two New 1,1,3,3-Tetramethylguanidinium Halochromates (C5H14N3CrO3X) (X: Cl, F): Efficient Reagents for Oxidation of Organic Substrates under Solvent-Free Conditions and Microwave Irradiation |
| title_short | Two New 1,1,3,3-Tetramethylguanidinium Halochromates (C5H14N3CrO3X) (X: Cl, F): Efficient Reagents for Oxidation of Organic Substrates under Solvent-Free Conditions and Microwave Irradiation |
| title_sort | two new 1 1 3 3 tetramethylguanidinium halochromates c5h14n3cro3x x cl f efficient reagents for oxidation of organic substrates under solvent free conditions and microwave irradiation |
| url | http://dx.doi.org/10.1155/2016/3518102 |
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