Hydrogeochemical processes, characterization and groundwater quality evaluation in Southwestern Punjab, India

Abstract Groundwater quality assessment is critical due to its susceptibility to a range of natural and anthropogenic influences, which, if unmanaged, can pose serious environmental and public health risks. This study investigates the hydrogeochemical characteristics and groundwater quality evaluati...

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Main Authors: Gopal Krishan, Vivek Diwakar, S. D. Khobragade, Guillaume Zuffinetti, Vaishali Singh, Rajesh Vashisht, Amandeep Kaur, Praveen Kumar, N. R. Allaka
Format: Article
Language:English
Published: Springer 2025-08-01
Series:Discover Water
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Online Access:https://doi.org/10.1007/s43832-025-00272-4
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author Gopal Krishan
Vivek Diwakar
S. D. Khobragade
Guillaume Zuffinetti
Vaishali Singh
Rajesh Vashisht
Amandeep Kaur
Praveen Kumar
N. R. Allaka
author_facet Gopal Krishan
Vivek Diwakar
S. D. Khobragade
Guillaume Zuffinetti
Vaishali Singh
Rajesh Vashisht
Amandeep Kaur
Praveen Kumar
N. R. Allaka
author_sort Gopal Krishan
collection DOAJ
description Abstract Groundwater quality assessment is critical due to its susceptibility to a range of natural and anthropogenic influences, which, if unmanaged, can pose serious environmental and public health risks. This study investigates the hydrogeochemical characteristics and groundwater quality evaluation in the southwestern districts of Punjab, India, with a focus on sustainable resource management. A total of 242 groundwater samples were systematically collected during the summer of 2019 across the districts of Mansa, Fazilka, Muktsar, Bathinda, Firozpur, and Faridkot. The samples were analyzed for almost all major cations, anions and other physicochemical parameters. Relative abundance of cations was Na+ > Mg2+ > Ca2+ > K & anions were SO4 2− > HCO3 − > Cl− > NO3 − > F. Elevated concentrations of sulphate & nitrate were detected, highlighting the impact of agrochemical inputs. The plots of Wilcox and USSL plots revealed a declining trend in groundwater suitability for irrigation, affecting both shallow and deep aquifer sources, due to increasing salinity and sodium hazards. Hydrochemical data was interpreted using Gibbs diagram, Piper’s trilinear plot and Durov diagram to understand the various geochemical processes affecting the groundwater quality. Hydrochemical analysis indicates that rock–water interactions, evaporation & anthropogenic processes predominantly control groundwater composition, as evidenced by high levels of sodium and chloride. This study is significant as the surface water resources are limited and the quality and quantity of groundwater are deteriorating with time due to anthropogenic inputs. These findings underscore the necessity of continuous monitoring and informed groundwater management strategies to mitigate contamination and ensure long-term sustainability.
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spelling doaj-art-003295eae77e4c3d99634022dec220632025-08-20T03:42:03ZengSpringerDiscover Water2730-647X2025-08-015111610.1007/s43832-025-00272-4Hydrogeochemical processes, characterization and groundwater quality evaluation in Southwestern Punjab, IndiaGopal Krishan0Vivek Diwakar1S. D. Khobragade2Guillaume Zuffinetti3Vaishali Singh4Rajesh Vashisht5Amandeep Kaur6Praveen Kumar7N. R. Allaka8National Institute of HydrologyNational Institute of HydrologyNational Institute of HydrologyUniversité Paris-Saclay, CentraleSupélec, CNRS, GeePsNational Institute of HydrologyPWRDACGWBIndian Institute TechnologyNational Institute of HydrologyAbstract Groundwater quality assessment is critical due to its susceptibility to a range of natural and anthropogenic influences, which, if unmanaged, can pose serious environmental and public health risks. This study investigates the hydrogeochemical characteristics and groundwater quality evaluation in the southwestern districts of Punjab, India, with a focus on sustainable resource management. A total of 242 groundwater samples were systematically collected during the summer of 2019 across the districts of Mansa, Fazilka, Muktsar, Bathinda, Firozpur, and Faridkot. The samples were analyzed for almost all major cations, anions and other physicochemical parameters. Relative abundance of cations was Na+ > Mg2+ > Ca2+ > K & anions were SO4 2− > HCO3 − > Cl− > NO3 − > F. Elevated concentrations of sulphate & nitrate were detected, highlighting the impact of agrochemical inputs. The plots of Wilcox and USSL plots revealed a declining trend in groundwater suitability for irrigation, affecting both shallow and deep aquifer sources, due to increasing salinity and sodium hazards. Hydrochemical data was interpreted using Gibbs diagram, Piper’s trilinear plot and Durov diagram to understand the various geochemical processes affecting the groundwater quality. Hydrochemical analysis indicates that rock–water interactions, evaporation & anthropogenic processes predominantly control groundwater composition, as evidenced by high levels of sodium and chloride. This study is significant as the surface water resources are limited and the quality and quantity of groundwater are deteriorating with time due to anthropogenic inputs. These findings underscore the necessity of continuous monitoring and informed groundwater management strategies to mitigate contamination and ensure long-term sustainability.https://doi.org/10.1007/s43832-025-00272-4Groundwater qualitySouthwestern PunjabAgricultural pollutionRock–water interactionHydrochemical processesGeochemical reactions
spellingShingle Gopal Krishan
Vivek Diwakar
S. D. Khobragade
Guillaume Zuffinetti
Vaishali Singh
Rajesh Vashisht
Amandeep Kaur
Praveen Kumar
N. R. Allaka
Hydrogeochemical processes, characterization and groundwater quality evaluation in Southwestern Punjab, India
Discover Water
Groundwater quality
Southwestern Punjab
Agricultural pollution
Rock–water interaction
Hydrochemical processes
Geochemical reactions
title Hydrogeochemical processes, characterization and groundwater quality evaluation in Southwestern Punjab, India
title_full Hydrogeochemical processes, characterization and groundwater quality evaluation in Southwestern Punjab, India
title_fullStr Hydrogeochemical processes, characterization and groundwater quality evaluation in Southwestern Punjab, India
title_full_unstemmed Hydrogeochemical processes, characterization and groundwater quality evaluation in Southwestern Punjab, India
title_short Hydrogeochemical processes, characterization and groundwater quality evaluation in Southwestern Punjab, India
title_sort hydrogeochemical processes characterization and groundwater quality evaluation in southwestern punjab india
topic Groundwater quality
Southwestern Punjab
Agricultural pollution
Rock–water interaction
Hydrochemical processes
Geochemical reactions
url https://doi.org/10.1007/s43832-025-00272-4
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