A new strategy for developing a Nb microalloyed fire-resistant steel: Effects of boron and cooling rate

This study investigates the correlation among cooling rates, boron addition, and their subsequent effects on the microstructure and mechanical properties of niobium microalloyed steels, specifically with an intent to develop new fire-resistant steels. Slower cooling rates enhanced the ferrite transf...

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Main Authors: A.M. Ferreira, E.A. Ariza, L.F. Bauri, P.M.C.D. Gomes, F.M.S.B. Carvalho, M. Masoumi, J.D. Poplawsky, H. Goldenstein, A.P. Tschiptschin
Format: Article
Language:English
Published: Elsevier 2024-11-01
Series:Journal of Materials Research and Technology
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Online Access:http://www.sciencedirect.com/science/article/pii/S2238785424021549
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author A.M. Ferreira
E.A. Ariza
L.F. Bauri
P.M.C.D. Gomes
F.M.S.B. Carvalho
M. Masoumi
J.D. Poplawsky
H. Goldenstein
A.P. Tschiptschin
author_facet A.M. Ferreira
E.A. Ariza
L.F. Bauri
P.M.C.D. Gomes
F.M.S.B. Carvalho
M. Masoumi
J.D. Poplawsky
H. Goldenstein
A.P. Tschiptschin
author_sort A.M. Ferreira
collection DOAJ
description This study investigates the correlation among cooling rates, boron addition, and their subsequent effects on the microstructure and mechanical properties of niobium microalloyed steels, specifically with an intent to develop new fire-resistant steels. Slower cooling rates enhanced the ferrite transformation and (Nb,Ti)C precipitation, promoting a shift toward an equilibrium-phase microstructure. A boron addition of 30 ppm was sufficient to increase the fire resistance of niobium microalloyed steels when slowly cooled after thermocontrolled rolling. At rapid cooling rate boron induced the formation of upper bainite. Boron is mainly segregated at the interface of (Nb,Ti)C precipitates, possibly hindering the coarsening kinetics of nanosized carbides and contributing to the maintenance of a high yield strength during fire exposure simulations. The boron addition promoted a ratio between yield strength at 600 °C and room temperature greater than 66%., boron also shifted the strain-temperature curve to higher temperatures in transient tensile tests. These findings contribute to the potential use of boron additions in advancing cost-effective, high-performance, fire-resistant steel development, highlighting the central role of microstructural control and optimized thermomechanical treatment.
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spelling doaj-art-fc874895a75a4ea081d0935db602316d2024-12-26T08:53:52ZengElsevierJournal of Materials Research and Technology2238-78542024-11-013323652376A new strategy for developing a Nb microalloyed fire-resistant steel: Effects of boron and cooling rateA.M. Ferreira0E.A. Ariza1L.F. Bauri2P.M.C.D. Gomes3F.M.S.B. Carvalho4M. Masoumi5J.D. Poplawsky6H. Goldenstein7A.P. Tschiptschin8Universidade de São Paulo, Escola Politécnica, Departamento de Engenharia Metalúrgica e de Materiais, São Paulo, SP, BrazilUniversidade de São Paulo, Escola Politécnica, Departamento de Engenharia Metalúrgica e de Materiais, São Paulo, SP, Brazil; Universidad del Magdalena, Grupo de Nuevos Materiales, Santa Marta, Magdalena, ColombiaUniversidade de São Paulo, Escola Politécnica, Departamento de Engenharia Metalúrgica e de Materiais, São Paulo, SP, BrazilUniversidade de São Paulo, Escola Politécnica, Departamento de Engenharia Metalúrgica e de Materiais, São Paulo, SP, BrazilUniversidade de São Paulo, Escola Politécnica, Departamento de Engenharia Metalúrgica e de Materiais, São Paulo, SP, Brazil; Instituto de Pesquisas Tecnológicas (IPT), São Paulo, SP, BrazilUniversidade Federal do ABC, Centro de Engenharia, Modelagem e Ciências Sociais Aplicadas, Santo André, SP, BrazilCenter for Nanophase Materials Sciences, Oak Ridge National Laboratory, 37831, Oak Ridge, TN, USAUniversidade de São Paulo, Escola Politécnica, Departamento de Engenharia Metalúrgica e de Materiais, São Paulo, SP, BrazilUniversidade de São Paulo, Escola Politécnica, Departamento de Engenharia Metalúrgica e de Materiais, São Paulo, SP, Brazil; Corresponding author.This study investigates the correlation among cooling rates, boron addition, and their subsequent effects on the microstructure and mechanical properties of niobium microalloyed steels, specifically with an intent to develop new fire-resistant steels. Slower cooling rates enhanced the ferrite transformation and (Nb,Ti)C precipitation, promoting a shift toward an equilibrium-phase microstructure. A boron addition of 30 ppm was sufficient to increase the fire resistance of niobium microalloyed steels when slowly cooled after thermocontrolled rolling. At rapid cooling rate boron induced the formation of upper bainite. Boron is mainly segregated at the interface of (Nb,Ti)C precipitates, possibly hindering the coarsening kinetics of nanosized carbides and contributing to the maintenance of a high yield strength during fire exposure simulations. The boron addition promoted a ratio between yield strength at 600 °C and room temperature greater than 66%., boron also shifted the strain-temperature curve to higher temperatures in transient tensile tests. These findings contribute to the potential use of boron additions in advancing cost-effective, high-performance, fire-resistant steel development, highlighting the central role of microstructural control and optimized thermomechanical treatment.http://www.sciencedirect.com/science/article/pii/S2238785424021549Fire-resistant steelsNiobium microalloyed steelsFire simulation testsNanoprecipitates
spellingShingle A.M. Ferreira
E.A. Ariza
L.F. Bauri
P.M.C.D. Gomes
F.M.S.B. Carvalho
M. Masoumi
J.D. Poplawsky
H. Goldenstein
A.P. Tschiptschin
A new strategy for developing a Nb microalloyed fire-resistant steel: Effects of boron and cooling rate
Journal of Materials Research and Technology
Fire-resistant steels
Niobium microalloyed steels
Fire simulation tests
Nanoprecipitates
title A new strategy for developing a Nb microalloyed fire-resistant steel: Effects of boron and cooling rate
title_full A new strategy for developing a Nb microalloyed fire-resistant steel: Effects of boron and cooling rate
title_fullStr A new strategy for developing a Nb microalloyed fire-resistant steel: Effects of boron and cooling rate
title_full_unstemmed A new strategy for developing a Nb microalloyed fire-resistant steel: Effects of boron and cooling rate
title_short A new strategy for developing a Nb microalloyed fire-resistant steel: Effects of boron and cooling rate
title_sort new strategy for developing a nb microalloyed fire resistant steel effects of boron and cooling rate
topic Fire-resistant steels
Niobium microalloyed steels
Fire simulation tests
Nanoprecipitates
url http://www.sciencedirect.com/science/article/pii/S2238785424021549
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