Visible-light-induced reusable decatungstate-photocatalyzed radical cascade alkylation/cyclization of isocyanides with simple alkanes, ethers and ketones

With reusable sodium decatungstate (NaDT) as the photocatalyst, hydrocarbons (alkanes, ethers and ketones) as the alkylating agents, a wide range of alkylated fused N-heterocycles were obtained in high yield.

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Main Authors: Ke-Li Wang, Hong-Tao Ji, Qiong-Hui Peng, Jun Jiang, Li-Juan Ou, Wei-Min He
Format: Article
Language:English
Published: KeAi Communications Co. Ltd. 2025-02-01
Series:Green Synthesis and Catalysis
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Online Access:http://www.sciencedirect.com/science/article/pii/S2666554924000036
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author Ke-Li Wang
Hong-Tao Ji
Qiong-Hui Peng
Jun Jiang
Li-Juan Ou
Wei-Min He
author_facet Ke-Li Wang
Hong-Tao Ji
Qiong-Hui Peng
Jun Jiang
Li-Juan Ou
Wei-Min He
author_sort Ke-Li Wang
collection DOAJ
description With reusable sodium decatungstate (NaDT) as the photocatalyst, hydrocarbons (alkanes, ethers and ketones) as the alkylating agents, a wide range of alkylated fused N-heterocycles were obtained in high yield.
format Article
id doaj-art-e9dba9f757bd40e88a3674dae8fef67c
institution DOAJ
issn 2666-5549
language English
publishDate 2025-02-01
publisher KeAi Communications Co. Ltd.
record_format Article
series Green Synthesis and Catalysis
spelling doaj-art-e9dba9f757bd40e88a3674dae8fef67c2025-08-20T02:45:50ZengKeAi Communications Co. Ltd.Green Synthesis and Catalysis2666-55492025-02-016110610910.1016/j.gresc.2024.01.003Visible-light-induced reusable decatungstate-photocatalyzed radical cascade alkylation/cyclization of isocyanides with simple alkanes, ethers and ketonesKe-Li Wang0Hong-Tao Ji1Qiong-Hui Peng2Jun Jiang3Li-Juan Ou4Wei-Min He5School of Chemistry and Chemical Engineering, University of South China, Hengyang, 421001, ChinaSchool of Chemistry and Chemical Engineering, University of South China, Hengyang, 421001, ChinaSchool of Chemistry and Chemical Engineering, University of South China, Hengyang, 421001, ChinaSchool of Chemistry and Chemical Engineering, University of South China, Hengyang, 421001, ChinaSchool of Chemistry and Chemical Engineering, University of South China, Hengyang, 421001, ChinaCorresponding author.; School of Chemistry and Chemical Engineering, University of South China, Hengyang, 421001, ChinaWith reusable sodium decatungstate (NaDT) as the photocatalyst, hydrocarbons (alkanes, ethers and ketones) as the alkylating agents, a wide range of alkylated fused N-heterocycles were obtained in high yield.http://www.sciencedirect.com/science/article/pii/S2666554924000036Visible-light catalysisCoupling reactionGreen chemistryHeterogeneous catalysis
spellingShingle Ke-Li Wang
Hong-Tao Ji
Qiong-Hui Peng
Jun Jiang
Li-Juan Ou
Wei-Min He
Visible-light-induced reusable decatungstate-photocatalyzed radical cascade alkylation/cyclization of isocyanides with simple alkanes, ethers and ketones
Green Synthesis and Catalysis
Visible-light catalysis
Coupling reaction
Green chemistry
Heterogeneous catalysis
title Visible-light-induced reusable decatungstate-photocatalyzed radical cascade alkylation/cyclization of isocyanides with simple alkanes, ethers and ketones
title_full Visible-light-induced reusable decatungstate-photocatalyzed radical cascade alkylation/cyclization of isocyanides with simple alkanes, ethers and ketones
title_fullStr Visible-light-induced reusable decatungstate-photocatalyzed radical cascade alkylation/cyclization of isocyanides with simple alkanes, ethers and ketones
title_full_unstemmed Visible-light-induced reusable decatungstate-photocatalyzed radical cascade alkylation/cyclization of isocyanides with simple alkanes, ethers and ketones
title_short Visible-light-induced reusable decatungstate-photocatalyzed radical cascade alkylation/cyclization of isocyanides with simple alkanes, ethers and ketones
title_sort visible light induced reusable decatungstate photocatalyzed radical cascade alkylation cyclization of isocyanides with simple alkanes ethers and ketones
topic Visible-light catalysis
Coupling reaction
Green chemistry
Heterogeneous catalysis
url http://www.sciencedirect.com/science/article/pii/S2666554924000036
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