Quality evaluation of Eucommiae Folium extracts and discovery of efficacy-associated quality markers based on spectrum-effect relationship

The spectrum-effect relationship between chemical fingerprints and antioxidant activities was established to evaluate the quality of Eucommiae Folium (EF) extracts and discover potential efficacy-associated quality markers. Characteristic fingerprints of different batches of EF extracts were generat...

Full description

Saved in:
Bibliographic Details
Main Authors: Weiwei Zhou, Xuefeng Wang, Juan Yang, Jiahong Dou, Yuelong Sun, Mengjie Zhang, Jun Li, Xiumei Li
Format: Article
Language:English
Published: Taylor & Francis Group 2023-09-01
Series:International Journal of Food Properties
Subjects:
Online Access:https://www.tandfonline.com/doi/10.1080/10942912.2023.2209703
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1846095421307355136
author Weiwei Zhou
Xuefeng Wang
Juan Yang
Jiahong Dou
Yuelong Sun
Mengjie Zhang
Jun Li
Xiumei Li
author_facet Weiwei Zhou
Xuefeng Wang
Juan Yang
Jiahong Dou
Yuelong Sun
Mengjie Zhang
Jun Li
Xiumei Li
author_sort Weiwei Zhou
collection DOAJ
description The spectrum-effect relationship between chemical fingerprints and antioxidant activities was established to evaluate the quality of Eucommiae Folium (EF) extracts and discover potential efficacy-associated quality markers. Characteristic fingerprints of different batches of EF extracts were generated by high-performance liquid chromatography (HPLC), and a similarity analysis was performed by hierarchical cluster analysis (HCA). Then the total antioxidant capacity assay kit with ferric reducing antioxidant assay (FRAP) method was used to determine antioxidant activity. The spectrum-effect relationship was established to identify the chemical constituents that impart antioxidant activities of Eucommiae Folium (EF) extracts using partial least squares regression (PLSR). HPLC fingerprints of EF extracts were established with the optimized chromatographic conditions: the mobile phase consisted 0.1% phosphoric acid -water (A) and acetonitrile (B), the detection wavelength was 326 nm, the column temperature was 30°C, and the flow rate was 0.8 mL/min. The correlation coefficient of similarity between 12 batches of extracts was ≥0.995. Compounds corresponding peaks P1, P2, P6 (chlorogenic acid), and P8 were closely related to the stable antioxidant activities of EF extracts, and could be selected as potential quality markers. An agile and efficient method that can ensure the intra-assay stability of biological activity of EF extracts and discover efficacy-associated quality markers was successfully built based on spectrum-effect relationship.
format Article
id doaj-art-ccf8b08935e34258bebdd517be13a374
institution Kabale University
issn 1094-2912
1532-2386
language English
publishDate 2023-09-01
publisher Taylor & Francis Group
record_format Article
series International Journal of Food Properties
spelling doaj-art-ccf8b08935e34258bebdd517be13a3742025-01-02T10:41:35ZengTaylor & Francis GroupInternational Journal of Food Properties1094-29121532-23862023-09-012611264127610.1080/10942912.2023.2209703Quality evaluation of Eucommiae Folium extracts and discovery of efficacy-associated quality markers based on spectrum-effect relationshipWeiwei Zhou0Xuefeng Wang1Juan Yang2Jiahong Dou3Yuelong Sun4Mengjie Zhang5Jun Li6Xiumei Li7Key Laboratory of Feed Biotechnology, Ministry of Agriculture and Rural Affairs, Institute of Feed Research of Chinese Academy of Agricultural Sciences, Beijing, ChinaCollege of pharmacy, Harbin University of Commerce, Harbin, ChinaKey Laboratory of Feed Biotechnology, Ministry of Agriculture and Rural Affairs, Institute of Feed Research of Chinese Academy of Agricultural Sciences, Beijing, ChinaState Key Laboratory of Food Nutrition and Safety, Key Laboratory of Industrial Fermentation Microbiology of Ministry of Education & Tianjin Key Laboratory of Industrial Microbiology, College of Biotechnology, Tianjin University of Science and Technology, Tianjin, ChinaKey Laboratory of Feed Biotechnology, Ministry of Agriculture and Rural Affairs, Institute of Feed Research of Chinese Academy of Agricultural Sciences, Beijing, ChinaKey Laboratory of Feed Biotechnology, Ministry of Agriculture and Rural Affairs, Institute of Feed Research of Chinese Academy of Agricultural Sciences, Beijing, ChinaKey Laboratory of Feed Biotechnology, Ministry of Agriculture and Rural Affairs, Institute of Feed Research of Chinese Academy of Agricultural Sciences, Beijing, ChinaKey Laboratory of Feed Biotechnology, Ministry of Agriculture and Rural Affairs, Institute of Feed Research of Chinese Academy of Agricultural Sciences, Beijing, ChinaThe spectrum-effect relationship between chemical fingerprints and antioxidant activities was established to evaluate the quality of Eucommiae Folium (EF) extracts and discover potential efficacy-associated quality markers. Characteristic fingerprints of different batches of EF extracts were generated by high-performance liquid chromatography (HPLC), and a similarity analysis was performed by hierarchical cluster analysis (HCA). Then the total antioxidant capacity assay kit with ferric reducing antioxidant assay (FRAP) method was used to determine antioxidant activity. The spectrum-effect relationship was established to identify the chemical constituents that impart antioxidant activities of Eucommiae Folium (EF) extracts using partial least squares regression (PLSR). HPLC fingerprints of EF extracts were established with the optimized chromatographic conditions: the mobile phase consisted 0.1% phosphoric acid -water (A) and acetonitrile (B), the detection wavelength was 326 nm, the column temperature was 30°C, and the flow rate was 0.8 mL/min. The correlation coefficient of similarity between 12 batches of extracts was ≥0.995. Compounds corresponding peaks P1, P2, P6 (chlorogenic acid), and P8 were closely related to the stable antioxidant activities of EF extracts, and could be selected as potential quality markers. An agile and efficient method that can ensure the intra-assay stability of biological activity of EF extracts and discover efficacy-associated quality markers was successfully built based on spectrum-effect relationship.https://www.tandfonline.com/doi/10.1080/10942912.2023.2209703EF extractsSpectrum-effect relationshipAntioxidant activityQuality evaluationQuality markers
spellingShingle Weiwei Zhou
Xuefeng Wang
Juan Yang
Jiahong Dou
Yuelong Sun
Mengjie Zhang
Jun Li
Xiumei Li
Quality evaluation of Eucommiae Folium extracts and discovery of efficacy-associated quality markers based on spectrum-effect relationship
International Journal of Food Properties
EF extracts
Spectrum-effect relationship
Antioxidant activity
Quality evaluation
Quality markers
title Quality evaluation of Eucommiae Folium extracts and discovery of efficacy-associated quality markers based on spectrum-effect relationship
title_full Quality evaluation of Eucommiae Folium extracts and discovery of efficacy-associated quality markers based on spectrum-effect relationship
title_fullStr Quality evaluation of Eucommiae Folium extracts and discovery of efficacy-associated quality markers based on spectrum-effect relationship
title_full_unstemmed Quality evaluation of Eucommiae Folium extracts and discovery of efficacy-associated quality markers based on spectrum-effect relationship
title_short Quality evaluation of Eucommiae Folium extracts and discovery of efficacy-associated quality markers based on spectrum-effect relationship
title_sort quality evaluation of eucommiae folium extracts and discovery of efficacy associated quality markers based on spectrum effect relationship
topic EF extracts
Spectrum-effect relationship
Antioxidant activity
Quality evaluation
Quality markers
url https://www.tandfonline.com/doi/10.1080/10942912.2023.2209703
work_keys_str_mv AT weiweizhou qualityevaluationofeucommiaefoliumextractsanddiscoveryofefficacyassociatedqualitymarkersbasedonspectrumeffectrelationship
AT xuefengwang qualityevaluationofeucommiaefoliumextractsanddiscoveryofefficacyassociatedqualitymarkersbasedonspectrumeffectrelationship
AT juanyang qualityevaluationofeucommiaefoliumextractsanddiscoveryofefficacyassociatedqualitymarkersbasedonspectrumeffectrelationship
AT jiahongdou qualityevaluationofeucommiaefoliumextractsanddiscoveryofefficacyassociatedqualitymarkersbasedonspectrumeffectrelationship
AT yuelongsun qualityevaluationofeucommiaefoliumextractsanddiscoveryofefficacyassociatedqualitymarkersbasedonspectrumeffectrelationship
AT mengjiezhang qualityevaluationofeucommiaefoliumextractsanddiscoveryofefficacyassociatedqualitymarkersbasedonspectrumeffectrelationship
AT junli qualityevaluationofeucommiaefoliumextractsanddiscoveryofefficacyassociatedqualitymarkersbasedonspectrumeffectrelationship
AT xiumeili qualityevaluationofeucommiaefoliumextractsanddiscoveryofefficacyassociatedqualitymarkersbasedonspectrumeffectrelationship