Australian bushfire emissions result in enhanced polar stratospheric clouds

<p>Extreme bushfire events amplify climate change by emitting greenhouse gases and destroying carbon sinks. They also cause economic damage, through property destruction, and even fatalities. One such bushfire occurred in Australia in 2019–2020, and this event injected large amounts of aerosol...

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Main Authors: S. Prasanth, N. S. Anand, K. Sunilkumar, S. Jose, K. Arun, S. K. Satheesh, K. K. Moorthy
Format: Article
Language:English
Published: Copernicus Publications 2025-07-01
Series:Atmospheric Chemistry and Physics
Online Access:https://acp.copernicus.org/articles/25/7161/2025/acp-25-7161-2025.pdf
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author S. Prasanth
S. Prasanth
N. S. Anand
K. Sunilkumar
S. Jose
K. Arun
S. K. Satheesh
S. K. Satheesh
S. K. Satheesh
K. K. Moorthy
author_facet S. Prasanth
S. Prasanth
N. S. Anand
K. Sunilkumar
S. Jose
K. Arun
S. K. Satheesh
S. K. Satheesh
S. K. Satheesh
K. K. Moorthy
author_sort S. Prasanth
collection DOAJ
description <p>Extreme bushfire events amplify climate change by emitting greenhouse gases and destroying carbon sinks. They also cause economic damage, through property destruction, and even fatalities. One such bushfire occurred in Australia in 2019–2020, and this event injected large amounts of aerosols and gases into the stratosphere and depleted the ozone layer. While previous studies have focused on the drivers behind ozone depletion, the bushfire impact on polar stratospheric clouds (PSCs), a paramount factor in ozone depletion, has not been extensively investigated so far. Therefore, this study focuses on the effects of bushfire aerosols on the dynamics and stratospheric chemistry related to PSC formation and its pathways. An analysis from Aura's Microwave Limb Sounder revealed that the enhanced hydrolysis of dinitrogen pentoxide significantly increased nitric acid (HNO<span class="inline-formula"><sub>3</sub></span>) in the high-latitude lower stratosphere in early 2020. This resulted in an anomalously high areal coverage of PSCs with ice, exceeding 3 standard deviations with respect to background period. Based on Lagrangian backward-trajectory analysis, we find that a predominant fraction (79 %) of the liquid–nitric acid trihydrate (NAT) mixture formed via the ice-free nucleation pathway. These NAT particles subsequently acted as nuclei for ice formation, accounting for 95 % of the observed ice PSCs. This rapid conversion from NAT to ice likely contributed to the strong positive anomaly in ice PSC. This highlights the primary formation pathways of ice and liquid–NAT mixtures and possibly helps us to simulate PSC formation and denitrification process better in climate models. These findings will contribute significantly to a deeper understanding of the impacts of extreme wildfire events on stratospheric chemistry and PSC dynamics.</p>
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spelling doaj-art-c4eb76abc3034c0b8aedd14bc7288b832025-08-20T03:50:17ZengCopernicus PublicationsAtmospheric Chemistry and Physics1680-73161680-73242025-07-01257161718610.5194/acp-25-7161-2025Australian bushfire emissions result in enhanced polar stratospheric cloudsS. Prasanth0S. Prasanth1N. S. Anand2K. Sunilkumar3S. Jose4K. Arun5S. K. Satheesh6S. K. Satheesh7S. K. Satheesh8K. K. Moorthy9Department of Physics and Electronics, Christ University, Bengaluru, Karnataka, IndiaDivecha Centre for Climate Change, Indian Institute of Science, Bengaluru, Karnataka, IndiaSchool of Earth, Environmental and Sustainability Sciences, Indian Institute of Science Education and Research Thiruvananthapuram, Vithura, Kerala, IndiaCentre for Atmospheric and Oceanic Sciences, Indian Institute of Science, Bengaluru, Karnataka, IndiaDepartment of Physics, Newman College, Thodupuzha, Kerala, IndiaDepartment of Physics and Electronics, Christ University, Bengaluru, Karnataka, IndiaDivecha Centre for Climate Change, Indian Institute of Science, Bengaluru, Karnataka, IndiaCentre for Atmospheric and Oceanic Sciences, Indian Institute of Science, Bengaluru, Karnataka, IndiaDST-Centre of Excellence in Climate Change, Indian Institute of Science, Bengaluru, Karnataka, IndiaDivecha Centre for Climate Change, Indian Institute of Science, Bengaluru, Karnataka, India<p>Extreme bushfire events amplify climate change by emitting greenhouse gases and destroying carbon sinks. They also cause economic damage, through property destruction, and even fatalities. One such bushfire occurred in Australia in 2019–2020, and this event injected large amounts of aerosols and gases into the stratosphere and depleted the ozone layer. While previous studies have focused on the drivers behind ozone depletion, the bushfire impact on polar stratospheric clouds (PSCs), a paramount factor in ozone depletion, has not been extensively investigated so far. Therefore, this study focuses on the effects of bushfire aerosols on the dynamics and stratospheric chemistry related to PSC formation and its pathways. An analysis from Aura's Microwave Limb Sounder revealed that the enhanced hydrolysis of dinitrogen pentoxide significantly increased nitric acid (HNO<span class="inline-formula"><sub>3</sub></span>) in the high-latitude lower stratosphere in early 2020. This resulted in an anomalously high areal coverage of PSCs with ice, exceeding 3 standard deviations with respect to background period. Based on Lagrangian backward-trajectory analysis, we find that a predominant fraction (79 %) of the liquid–nitric acid trihydrate (NAT) mixture formed via the ice-free nucleation pathway. These NAT particles subsequently acted as nuclei for ice formation, accounting for 95 % of the observed ice PSCs. This rapid conversion from NAT to ice likely contributed to the strong positive anomaly in ice PSC. This highlights the primary formation pathways of ice and liquid–NAT mixtures and possibly helps us to simulate PSC formation and denitrification process better in climate models. These findings will contribute significantly to a deeper understanding of the impacts of extreme wildfire events on stratospheric chemistry and PSC dynamics.</p>https://acp.copernicus.org/articles/25/7161/2025/acp-25-7161-2025.pdf
spellingShingle S. Prasanth
S. Prasanth
N. S. Anand
K. Sunilkumar
S. Jose
K. Arun
S. K. Satheesh
S. K. Satheesh
S. K. Satheesh
K. K. Moorthy
Australian bushfire emissions result in enhanced polar stratospheric clouds
Atmospheric Chemistry and Physics
title Australian bushfire emissions result in enhanced polar stratospheric clouds
title_full Australian bushfire emissions result in enhanced polar stratospheric clouds
title_fullStr Australian bushfire emissions result in enhanced polar stratospheric clouds
title_full_unstemmed Australian bushfire emissions result in enhanced polar stratospheric clouds
title_short Australian bushfire emissions result in enhanced polar stratospheric clouds
title_sort australian bushfire emissions result in enhanced polar stratospheric clouds
url https://acp.copernicus.org/articles/25/7161/2025/acp-25-7161-2025.pdf
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