A dynamic isotope effect in the nucleophilic substitution reaction between F− and CD3I

Abstract The influence of quantum mechanics on the dynamics of chemical reactions is unknown for many processes in chemistry. Chemical reaction dynamics are often well described by quasiclassical motion of the atoms on quantum mechanical Born-Oppenheimer potential energy surfaces. Here we present a...

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Bibliographic Details
Main Authors: Atilay Ayasli, Arnab Khan, Thomas Gstir, Tim Michaelsen, Dóra Papp, Yan Wang, Hongwei Song, Minghui Yang, Gábor Czakó, Roland Wester
Format: Article
Language:English
Published: Nature Portfolio 2025-03-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-025-57086-0
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