Poly[[bis(μ4-acetato-κ4O:O:O′:O′)tetrakis(μ3-acetato-κ3O:O:O′)bis(μ2-acetato-κ2O:O′)bis(μ3-hydroxido)pentanickel(II)] 2.60-hydrate]

Poly[[bis(μ4-acetato-κ4O:O:O′:O′)tetrakis(μ3-acetato-κ3O:O:O′)bis(μ2-acetato-κ2O:O′)bis(μ3-hydroxido)pentanickel(II)] 2.60-hydrate]

The title compound, {[Ni5(C2H3O2)8(OH)2]·2.60H2O}n or [Ni5(OAc)8(OH)2]·2.60H2O (OAc is the acetate anion, C2H3O2), represents a hydrated basic acetate. Its asymmetric unit comprises half of the formula unit, with one of the three unique NiII cations situated at an inversion centre. The NiII atoms ar...

Full description

Saved in:

Bibliographic Details
Main Authors:	Maximilian Pfeiffer, Berthold Stöger, Matthias Weil
Format:	Article
Language:	English
Published:	International Union of Crystallography 2025-02-01
Series:	IUCrData
Subjects:	crystal structure nickel basic acetate disorder hydrogen-bonding
Online Access:	https://journals.iucr.org/paper?S2414314625000823
Tags:	Add Tag No Tags, Be the first to tag this record!

Similar Items

The crystal structure of tetrakis(μ2-acetato-κ2 O:O′)-bis[(4′-phenyl-4,2′:6′,4″-terpyridine-κ1 N)dicopper(II)], C25H21CuN3O4
by: Duan Hong-Xin, et al.
Published: (2024-12-01)

Synthesis and crystal structure of catena-poly[[bis(nitrato-κ2O,O′)strontium(II)]-di-μ-l-histidine-κ3O,O′:O;κ2O:O′]
by: Sathish Marimuthu, et al.
Published: (2025-07-01)

Bis{µ-(2,2′-bipyridine-1κ<sup>2</sup><i>N</i>,<i>N′</i>)-(6,6′-dicarbonyl-1κ<sup>2</sup><i>O</i>,<i>O′</i>:2κ<i>O′</i>)bis(<i>N</i>,<i>N</i>-diethylthioureato-2κ<i>S</i>)}(acetato-1κ<i>O</i>)(µ-acetato-1κ<i>O</i>:2-κ<i>O′</i>)(methanol-2κ<i>O</i>)thoriumnickel
by: Christelle Njiki Noufele, et al.
Published: (2025-01-01)

catena-Poly[[[aquacopper(II)]-μ-hydroxido-κ2O:O-μ-[3-(4H-1,2,4-triazol-4-yl)benzoato]-κ2N1:N2] monohydrate]
by: Xiao-Yu Li, et al.
Published: (2025-07-01)

Crystal structure of poly[aqua-(μ 2-3-bromoisonicotinato-κ 2 N: O)-(μ 2-3-bromoisonicotinato-κ 3 N: O: O′)-(μ 3-3-bromoisonicotinato-κ 3 N: O: O′)-(μ 2-nitrite-κ 3 O: O′: O″)dicadmium(II) monohydrate], C19H12Br3Cd2N3O9
by: Li Kuan-Ying, et al.
Published: (2025-08-01)

Bis[N,N-bis(diphenylphosphanyl)cyclohexanamine-κ2P,P′]dichloridocobalt(III) tris(μ-diphenylphosphinato-κ2O:O′)bis[chloridocobaltate(II)]–dichloromethane–diethyl ether (1/1.189/0.811)
by: Sizwe J. Zamisa, et al.
Published: (2025-07-01)

STUDY ON SYNTHESIS AND CRYSTAL STRUCTURE OF TETRAKIS-(μ2-ACETATO)-DIHYDRATE-DICOPPER(II)
by: LI-HUA WANG
Published: (2015-10-01)

Crystal structure of poly[diaqua-(μ2-2,5-dihydroxyterephthalato-κ2O:O′)(μ2-bis(4-pyridylformyl)piperazine-κ2N:N′)cadmium(II)] dihydrate, C24H28CdN4O12
by: Lv Benlian, et al.
Published: (2021-09-01)

Crystal structure of bis(µ2- 4-iodopyridine-2,6-dicarboxylato-κ3O:N:O′)-bis(4-iodopyridine-2,6-dicarboxylato-κ3O:N:O′)-bis(µ2-1-(4-pyridyl)piperazine-κ2N:N′)-hexa-aqua-tetra-copper(II), C46H46Cu4I4N10O22
by: Lv Benlian
Published: (2021-09-01)

Crystal structure of poly[μ3-acetato-diaqua-μ3-sulfato-cerium(III)]: serendipitous synthesis of a layered coordination polymer exhibiting interlayer O—H...O hydrogen bonding
by: Niklas Ruser, et al.
Published: (2025-02-01)

Bis(μ-thiosemicarbazide-κ3N1,S:S;κ3S:N1,S)bis[(dimethylformamide-κO)(thiosemicarbazide-κ2N1,S)cadmium(II)] tetrakis(2,4,6-trinitrophenolate): synthesis, crystal structure and Hirshfeld surface analysis
by: R. Santhakumari, et al.
Published: (2025-06-01)

(Nitrito-κ2O:O′)bis[tris(4-fluorophenyl)phosphine-κP]silver(I)
by: Frederick P. Malan, et al.
Published: (2025-04-01)

Crystal structure of poly[hexaqua-pentakis(μ4-2,2′-bipyridine-4,4′-dicarboxylato-κ4 O:O′:O″:O‴)-(μ2-2,2′-bipyridine-4,4′-dicarboxylato-κ2 O:O)tetraytterbium(III)] hydrate, C36H26N6O16Yb2
by: Cheng Zheng, et al.
Published: (2025-02-01)

Hydrothermal synthesis and crystal structure of catena-poly[(1,10-phenanthroline-κ 2 N,N′)-bis(μ 2-nitroisophthalato-κ 3 O,O′:O″)nickel(II)], C20H13NiN3O7
by: Wen-Jie Bi, et al.
Published: (2025-02-01)

Crystal structure of poly[(μ3-3, 5-dichloro-2-hydroxy-benzoato-κ4 Cl,O:O′:O″) silver(I)], C7H3AgCl2O3
by: Jiang Jin-Ke, et al.
Published: (2023-08-01)

On the flexibility of the multipole model refinement. A DFT benchmark study of the tetrakis(μ-acetato)diaquadicopper model system
by: Andrej Hlinčík, et al.
Published: (2025-07-01)

Crystal structure of catena-poly[(μ3-4,4′-oxydibenzoato- κ5 O,O′: O″,O‴:O‴)-bis(2,4,6-tri(3-pyridine)-1,3,5-triazine-κ1 N)cadmium(II)], C50H32CdN12O5
by: Jing Hao, et al.
Published: (2025-06-01)

Whole-molecule disorder of the heterometallic complex diaqua-1κ2O-dichlorido-2κ2Cl-(μ-2-formyl-6-methoxyphenolato-1κ2O1,O2:2κO6){μ-2-methoxy-6-[(methylimino)methyl]phenolato-1κ2N,O1:2κO6}lead(II)nickel(II)
by: Olga Yu. Vassilyeva, et al.
Published: (2025-08-01)

Bis[(2-methoxyphenyl)diphenylphosphane-κP](nitrito-κ2O,O′)silver(I)
by: Frederick P. Malan, et al.
Published: (2025-03-01)

The crystal structure of bis{tetrakis(n-butyl)(μ-hydroxy)(2,3,5,6-tetrafluorobenzoate) (μ 3-oxo)ditin(IV)}
by: He Lifang, et al.
Published: (2025-08-01)

Crystal structure of poly[[aqua(μ2-pyrazine-κ2N:N′)(μ2-2,3,5,6-tetrachlorobenzene-1,4-dicarboxylato-κ2O1:O4)copper(II)] hemihydrate]
by: Hitoshi Kumagai, et al.
Published: (2025-05-01)

The crystal structure of bis[μ2-(3-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)propanoate-κ2O:N)-bis(2,2′-bipyridine-κ2 N, N′)dicopper(II)]dinitrate, C42H36Cu2N12O10
by: Tang Zhiwei, et al.
Published: (2025-02-01)

Crystal structure of poly[(μ2-1-(1-imidazolyl)-4-(imidazol-1-ylmethyl)benzene-κ2N:N′)-(μ3-pyridazine-4,5-dicarboxylate-κ3O:O′:N)]copper(II) hydrate, C19H16CuN6O5
by: Liu Guang-Zhen, et al.
Published: (2022-08-01)

The crystal structure of (μ4-oxo)-tri(μ4-2,2′-bipyridine-6,6′-bis(olato)-κ5 O,O′:N:N′:O″)tetrazinc(II) – methylformamide (1/1), C33H25N7O8Zn4
by: Shi Zhen-Zhen, et al.
Published: (2025-02-01)

Crystal structure of catena-poly[aqua-(μ 2(3,4-dimethylthieno[2,3-b]thiophene-2,5-dicarboxylato-κ 2 O:O′)-(3,6-bis(4′-pyridyl)-1,2,4,5-tetrazine-κ 1 N)zinc(II)], C22H16N6O5S2Zn
by: Liu Nana, et al.
Published: (2025-08-01)

Crystal structure of poly[(μ 2-2,2′-[1,4-phenylenebis(methylenesulfanediyl)]dibenzoato-κ 4 O,O′:O″,O‴)-(μ 2-1,1′-([1,1′-biphenyl]-4,4′-diyl)bis(1H-benzimidazole)-κ 2 N:N′)cadmium(II)]dimethylformamide solvate, C51H41N5O5S2Cd
by: Li Bin, et al.
Published: (2025-08-01)

The crystal structure of bis(μ2-5-chloro-2-oxido-N-(1-oxidopropylidene)benzohydrazonato-κ5 N,O,O′:N′,O′′)-octakis(pyridine-κ1 N)trinickel(II) C60H56Cl2N12Ni3O6
by: Xin Wang, et al.
Published: (2022-08-01)

The crystal structure of (4-hydroxybenzenesulfonate)-k1O-6,6′-((1E,1′E)- (ethane-1,2-diylbis(azaneylylidene))bis(methaneylylidene)) bis(2-methoxyphenol)-κ2N,N,μ2O,O,κ2O, O)-(methanol)-cobalt(II) sodium(I), C25H27CoN2NaO9S
by: Zhang Shaoliang, et al.
Published: (2023-10-01)

The crystal structure of catena-((μ 2-4,4′-bipyridine-κ 2 N:N′)-bis(4-fluorobenzoato-κ1O)-copper(II)), C24H16F2N2O4Cu
by: Chen Wentao, et al.
Published: (2025-08-01)

Crystal structure of (μ2-1-(4,4′-bipyridine-κ2N:N′)-bis[diaqua-(4-iodopyridine-2,6-dicarboxylato-κ3O,N,O′)–cobalt(II)], C24H20Co2I2N4O12
by: Hong Dong-Feng, et al.
Published: (2023-10-01)

Synthesis, crystal structure and Hirshfeld surface analysis of bis[2-amino-5-(ethylsulfanyl)-1,3,4-thiadiazol-3-ium] bis(perchlorato-κO)bis(picolinato-κ2N,O)copper(II)
by: Gulnaz Khojabaeva, et al.
Published: (2025-07-01)

The crystal structure of poly[(μ 2-1-(1-imidazolyl)-4- (imidazol-1′-yl-methyl)benzene κ 2 N:N′)-(μ 2-3-nitrobenzene -1,2-dicarboxylato-k4,O,O′:O′′,O′′′]zinc(II)-κ 2, C21H15N5O6Zn
by: Li Gui-Lian, et al.
Published: (2025-08-01)

Crystal structure of (μ2-7-{[bis(pyridin-2-ylmethyl)amino-1κ3N,N′,N′′]methyl}-5-chloroquinolin-8-olato-2κN;1:2κ2O)trichlorido-1κCl,2κ2Cl-dizinc(II)
by: Koji Kubono, et al.
Published: (2024-11-01)

LEWIS-BASE ADDUCTS OF LEAD(II) COMPOUNDS V,* SYNTHESIS AND STRUCTmAL CHARACTEREATION OF MONONUCLEAR (ACETATO-0,O') BIS(2,Zr-BIPYRIDINE) (PERCHLORATO-0,O') LEAD(II) AND BIS (2,Z'-BIPYRIDIW) BIS(PERCHL0RATO-0,O') LEAD(II)
Published: (1996-03-01)

The crystal structure of catena-poly[bis(6-phenylpyridine-2-carboxylato-κ2 N,O)-(μ2-4,4′-bipyridne-κ2 N:N)cadmium(II)], C34H24N4O4Cd
by: Ping Liu, et al.
Published: (2023-08-01)

The crystal structure of poly[(μ 3-imidazolato-κ 3 N:N:N′)(tetrahydrofuran- κ 1 O)lithium(I)], C7H11LiN2O
by: Zapf Ludwig, et al.
Published: (2021-09-01)

Crystal structure of poly[(μ 2-1,4-bis(imidazol-1-yl)benzene-k 2 N:N′)(μ 4-biphenyl-3,3′,5,5′-tetracarboxylic-k 4 O,O,O,O)dizinc(II)] dihydrate, C40H28Zn2N8O9
by: Yang Xufeng, et al.
Published: (2025-08-01)

The crystal structure of tetraaqua-bis(2-(2-methyl-5-nitro-1H-imidazol-1-yl)acetato-k2O:N)-tetrakis(2-(2-methyl-5-nitro-1H-imidazol-1-yl)acetato-k1N)trizinc(II) hexahydrate C36H52N18O32Zn3
by: Wang Ze-Lin, et al.
Published: (2025-06-01)

Crystal structure of catena-poly[(μ 2-(2-(1H-imidazol-1-ylmethyl)benzyl)-1H-imidazole κ2N:N′)- (μ 2-cyclohexane-1,2-dicarboxylato κ2O,O′)cobalt(II) monohydrate]
by: Lian Zhaoxun
Published: (2025-08-01)

The crystal structure of bis{chlorido-[μ2-(1-oxidopyridin-2-yl)(pyridin-2-yl)amido-κ3 O,N, N′]copper(II)}, C20H16Cl2Cu2N6O2
by: Liu Yinqiu
Published: (2025-04-01)